SDS Volume (1137)

Volume 57. Ethene, p None

Original Measurements

Grollman, A.; J. Biol. Chem. 1929, 82, 317-325.

Variables:

Room Temp: 310.65 $\pu{K}$
Pressure: 101.325 $\pu{kPa}$

Prepared by:

W. Hayduk

Method/Apparatus/Procedure:

A glass bubbling-type of saturator immersed in a constant temperature bath was used. The gas was presaturated with water vapor. A known volume of saturated solution was transferred over mercury into a Van Slyke desorption apparatus. Gas removed in three evacuations was transferred to a sample tube where the volume was determined and a sample of the gas was analyzed. The solubilities were expressed as the Bunsen coefficients.

Source and Purity of Materials:
  1. Ethene source and purity not given.
  2. Water distilled.
Estimated Errors:

Ambient temperature: δT/K = ±0.05
Mass concentration (m/v) (1): δβ/β = ±0.04 (complier)

Components:
  1. Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
  2. Water, $\ce{ H2O }$; [7732-18-5] NIST WebBook
Experimental Data
$T$ ($\pu{K}$) $T$ (°C) $x_{1}$ $L$ α ($\pu{cm3(g) cm-3(l) atm-1}$)
310.6537.5 6.34 x 10-50.08870.078

(1) Calculated by the compiler.

(2) Calculated by compiler using a gas molar volume at a temperature of 310.65 K and a pressure of 101.325 kPa of 25360 cm3 /mole.

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