Compilation - Ethene with Benzene (IUPAC SDS Volume 57)
SDS Volume (1129)
Volume 57. Ethene, p None
Original Measurements
Kozorezov, Yu. I.; Rusakov, A. P.; Pikalo, N. M.; Khim. Prom. 1969, 5, 343-5.
Variables:
Room Temp:
323.15 - 423.15
$\pu{K}$
Pressure:
0.25 - 1.54
$\pu{MPa}$
Prepared by:
Method/Apparatus/Procedure:
Single pass flow apparatus. Ethene allowed to flow through solvent for 3 to 5 hours. Liquid sample withdrawn and analysed by stripping out ethene and measuring amount volumetrically. Solvent in sample estimated gravimetrically.
Source and Purity of Materials:
- Purity 99.93 mole%.
- BP = 80°C; MP = 54°C; $d_{4}^{20}$ = 0.8796; $n_{D}^{20}$ = 1.5010.
Estimated Errors:
Ambient temperature: δT/K = ±0.5 (estimated by the compiler)
Mass concentration (m/v) (1): δxC2H4 = ±0.001 (estimated by compiler)
Pressure: δP/105Pa = ±0.1 (estimated by compiler)
Components:
- Ethene, $\ce{ C2H4 }$; [74-85-1] NIST WebBook
- Benzene, $\ce{ C6H6 }$; [71-43-2] NIST WebBook
Experimental Data
Henry’s constant given as atm/mole fraction as follows:
T/K 323.15 373.15 403.15 423.15
H, atm/mole fraction 115.2 181.0 204.0 229.0
| $T$ ($\pu{K}$) | $x_{1}$ | $P$ (Pa) | S ($\pu{cm3(g) cm-3(s) cmHg-1}$) |
|---|---|---|---|
| 323.15 | 0.020 | 2.5 x 10-5 | 6.0 |
| 323.15 | 0.040 | 5.1 x 10-5 | 11.9 |
| 323.15 | 0.081 | 1.01 x 10-4 | 25.4 |
| 323.15 | 0.122 | 1.52 x 10-4 | 39.9 |
| 373.15 | 4 x 10-3 | 2.5 x 10-5 | 1.3 |
| 373.15 | 0.017 | 5.1 x 10-5 | 5.1 |
| 373.15 | 0.043 | 1.01 x 10-4 | 13.0 |
| 373.15 | 0.072 | 1.52 x 10-4 | 22.3 |
| 403.15 | 6 x 10-3 | 5.1 x 10-5 | 1.7 |
| 403.15 | 0.030 | 1.01 x 10-4 | 8.6 |
| 403.15 | 0.051 | 1.52 x 10-4 | 14.9 |
| 423.15 | 3 x 10-3 | 6.6 x 10-5 | 1.0 |
| 423.15 | 0.010 | 1.01 x 10-4 | 5.1 |
| 423.15 | 0.047 | 1.52 x 10-4 | 12.1 |
(1) Calculated by compilers.
