Components:

(1) Ethylbenzene, C8H10; [100-41-4] NIST WebBook
(2) Water, H2O; [7732-18-5] NIST WebBook

Original Measurements

McAuliffe, C.; Nature 1963, 200, 1092-3.

Variables:

Ambient temperature: 25 °C

Prepared by:

Z. Maczynska, A. Maczynski

Method/Apparatus/Procedure:

The saturated solution of (1) in (2) was prepared by either shaking vigorously on a reciprocal shaker or stirring for several days with a magnetic stirrer. A 0.05 mL or 0.10 mL sample of the hydrocarbon-saturated water was injected directly into a gas liquid chromatograph.

Source and Purity of Materials:
  1. Phillips Petroleum Co.; 99+%; used as received.
  2. distilled.
Estimated Errors:

Ambient temperature: ±1.5°C
Mass concentration (m/v) (1): 0.0008 (std. dev. of mean)

Experimental Values:
Note: The solubility of ethylbenzene in water at 25°C was reported to be 0.0159 g(1)/100 g sln.
The corresponding mole fraction, x1, calculated by the compilers is 2.70 × 10-5.
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