SDS Volume

Volume 20. Halogenated Benzenes, Toluenes and Phenols with Water, p 123

Source Publication

Jockers, R.; Ph.D. Dissertation, University of Bochum, Bochum, 1976.

Conditions:

Room Temp: 260.0 - 280.0 °C

Compiler:

A.L. Horvath

Methodology:

The measurements were made using a high temperature, high pressure optical cell made from stainless steel with an internal stirrer. Predetermined mixtures of 1,4-difluorobenzene in water were introduced into the cell and homogenized at various temperatures and pressures. The phase transitions were observed through a sapphire window at the appropriate temperatures and pressures. Further details have been included in [1,2].

Sample Information:

1. Fluka AG., Buchs, Schweiz, 99.5% pure, redistilled before use.
2. Boiled with $\ce{KMnO4}$ and redistilled before use.

Measurement Errors:

Ambient temperature: ±0.5 K.
Mass concentration (m/v) (1): ±1%.
Pressure: ±2 bar.

Methodology Citations

¹ Gotze, G.; Jockers, R.; Schneider, G. M.; 4th Internat. Conf. Chem. Thermodyn. IUPAC, Montpellier, Aug. 26-30, 1975, Part IV/9, 57-64.
² Jockers, R.; Schneider, G. M.; Ber. Bunsenges. Phys. Chem. 1978, 83, 576-82.