{"compilation": {"title": "Solubility data from IUPAC SDS Volume 78 (page 1117) - Acetonitrile with (Methylthio)benzene", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Obolentsev, R. D.; Lebedeva, M. N.; Kreis, E. A.; Lyapina, N. K.; Parphenova, M. A.; Neftekhimiya 11, 893-901 (1971).", "pubtype": "paper"}], "system": "Acetonitrile with (Methylthio)benzene", "substances": [{"constituent": 1, "name": "Acetonitrile", "formula": "C2H3N", "molweight": 41.052, "casrn": "75-05-8", "inchi": "InChI=1S/C2H3N/c1-2-3/h1H3", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N", "sample": "Source not specified; purity not specified; dried and purified; BP = 81.6°C, $n_{D}^{20}$ = 1.3458."}, {"constituent": 2, "name": "(Methylthio)benzene", "formula": "C7H8S", "molweight": 124.21, "sample": "Synthesized in Institute of Chemistry (Upha, Russia)."}], "method": "The synthetic method was used. Samples of (1) and (2) of weight about 0.2 g were placed in glass ampoules of length 3 to 4 cm and inner diameter of 4 mm. After cooling in a mixture of ice with salt ampoules were sealed. Three to four ampoules were attached to a thermometer and placed in a glass bath with glycerine (for heating) or with acetone and solid $\\ce{CO2}$ (for cooling) with continuous stirring. The heating and cooling 2 K per minute. The UCST was determined by following the appearance and disappearance of the meniscus.", "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the binary systems acetonitrile (1) + (Methylthio)benzene (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "6.30e+01", "significand": "6.30", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.362e+02", "significand": "3.362", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.942e+02", "significand": "1.942", "exponent": "2", "sigfigs": "4", "unit": "°C"}], "data": [], "supplemental": []}]}]}}