{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/5090/jsonld#"}], "@id": "", "generatedAt": "10-17-26 01:26:29", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/5090/jsonld#", "@type": "sdo:scidataFramework", "uid": "78_171", "title": "Solubility data from IUPAC SDS Volume 78 (page 1095) - Acetonitrile with Hexadecyl hexanoate", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:K", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2 to 0.3 mm diameters) by dipping consecutively into both liquids. The height of the liquid was 7 to 10 mm. Room temperature solids were melted on a glass slide over a micro burner. The capillary was sealed at both ends to a length of 30 to 35 mm, then inserted in to the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Acetonitrile", "formula": "C2H3N", "casrn": "75-05-8", "iupacname": "acetonitrile", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Hexadecyl hexanoate", "formula": "C22H44O2", "casrn": "14331-11-4"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Acetonitrile", "description": "Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Hexadecyl hexanoate", "description": "Not specified.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Acetonitrile with Hexadecyl hexanoate", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.622e+02", "significand": 3.622, "exponent": 2, "sigfigs": 4}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "78:171:003:001:001", "conditions#": ["condition/1/"]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).", "doi": "10.1007/bf02635572", "url": "https://doi.org/10.1007/bf02635572"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 78 (page 1095) - Acetonitrile with Hexadecyl hexanoate", "url": "https://doi.org/10.1063/1.1494086"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}