{"compilation": {"title": "Solubility data from IUPAC SDS Volume 78 (page 1095) - Acetonitrile with Hexadecylbutanoate", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1007/bf02635572"}], "system": "Acetonitrile with Hexadecylbutanoate", "substances": [{"constituent": 1, "name": "Acetonitrile", "formula": "C2H3N", "molweight": 41.052, "casrn": "75-05-8", "inchi": "InChI=1S/C2H3N/c1-2-3/h1H3", "inchikey": "WEVYAHXRMPXWCK-UHFFFAOYSA-N", "sample": "Baker Chemical Co.; reagent No. 9011; $n_{D}^{20}$ = 1.3445, $d_{4}^{20}$ = 0.780."}, {"constituent": 2, "name": "Hexadecyl butanoate", "formula": "C20H40O2", "molweight": 312.53, "casrn": "6221-99-4", "inchi": "InChI=1S/C20H40O2/c1-3-5-6-7-8-9-10-11-12-13-14-15-16-17-19-22-20(21)18-4-2/h3-19H2,1-2H3", "inchikey": "NJVKAQGGBANCKG-UHFFFAOYSA-N", "sample": "Not specified."}], "method": "The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2 to 0.3 mm diameters) by dipping consecutively into both liquids. The height of the liquid was 7 to 10 mm. Room temperature solids were melted on a glass slide over a micro burner. The capillary was sealed at both ends to a length of 30 to 35 mm, then inserted in to the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.", "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the binary systems acetonitrile (1) + Hexadecyl butanoate (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "6.80e+01", "significand": "6.80", "exponent": "1", "sigfigs": "3", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.312e+02", "significand": "3.312", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}]}]}}