{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/1289/jsonld#"}], "@id": "", "generatedAt": "08-18-26 06:27:57", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/1289/jsonld#", "@type": "sdo:scidataFramework", "uid": "57_257", "title": "Solubility data from IUPAC SDS Volume 57 (page 341) - Ethene with Carbowax 350", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "H. Lawrence Clever", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["The authors describe three methods:<br/>1.A. [Saturat. n\u00b01]. A measure of the static pressure of saturation in an apparatus which gave a precision of 10 - 15 %.<br/>1.B. [Saturat. n\u00b02]. A measure of the static pressure of saturation in an apparatus which gave a precision of 2 - 5 %.<br/>2. [Chromato]. 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A gas liquid chromatographic method estimated to have a precision of 2 - 5 %.<br/>3. [Anal. directe]. Direct analysis of the gaseous and liquid phases.<p>Method 2 was used for these systems.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Ethene", "formula": "C2H4", "casrn": "74-85-1", "iupacname": "ethene", "inchikey": "VGGSQFUCUMXWEO-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Carbowax 350", "formula": "$\\ce{CH3O(CH2CH2O)_{n}H}$", "casrn": "9004-74-4"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Ethene", "description": "Ethene. Air Liquide. For narcosis, 99.9%.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Carbowax 350", "description": "Carbowax. Union Carbide.<br/>Polyethylene glycols.<br/>Carbowax 400 $M_{\\rm{w}} = \\pu{400 \\pm 20 g mol-1}$.<br/>Carbowax 350 $M_{\\rm{w}} = \\pu{350 \\pm 15 g mol-1}$.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Ethene with Carbowax 350", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "text": "293.15-313.15"}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "57:257:002:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "-"}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Henry's Law Solubility Coefficient", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.15e+01", "significand": 8.15, "exponent": 1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Enthalpy change", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.66e+00", "significand": 2.66, "exponent": 0, "sigfigs": 3}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Hannaert, H.; Haccuria, M.; Mathieu, M. 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