{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page 1251) - Nitromethane with Octadecane", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).", "pubtype": "paper", "url": "https://doi.org/10.1007/bf02635572"}], "system": "Nitromethane with Octadecane", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Fisher Scientific Co.; certified, No. N-98;<br/>$n_{D}^{20}$ = \\pu{1.3820}$, $\\rho^{20} = \\pu{1134 g L-1}$."}, {"constituent": 2, "name": "Octadecane", "formula": "C18H38", "molweight": 254.494, "casrn": "593-45-3", "inchi": "InChI=1S/C18H38/c1-3-5-7-9-11-13-15-17-18-16-14-12-10-8-6-4-2/h3-18H2,1-2H3", "inchikey": "RZJRJXONCZWCBN-UHFFFAOYSA-N", "sample": "Not specified."}], "method": "The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2-0.3 mm diameter) by dipping consecutively into both liquids. The height of the liquid was 7-10 mm. Room temperature solids were melted on a glass slide over a microburner. The capillary was sealed at both ends to a length of 30-35 mm, then inserted in to the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.", "dataset": [{"series": 1, "title": "Upper critical solution temperatures of the systems nitromethane (1) + Octadecane (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.590e+02", "significand": "1.590", "exponent": "2", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient temperature", "number": "4.322e+02", "significand": "4.322", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [], "supplemental": []}]}]}}