<compilation>
 <compilers>Valerii P. Sazonov</compilers>
 <dataset>
  <points>
   <conditions>
    <exponent>2</exponent>
    <number>1.420e+02</number>
    <property>Ambient temperature</property>
    <sigfigs>4</sigfigs>
    <significand>1.420</significand>
    <unit>&amp;deg;C</unit>
   </conditions>
   <conditions>
    <exponent>2</exponent>
    <number>4.152e+02</number>
    <property>Ambient temperature</property>
    <sigfigs>4</sigfigs>
    <significand>4.152</significand>
    <unit>$\pu{K}$</unit>
   </conditions>
   <data></data>
   <pntnum>1</pntnum>
   <supplemental></supplemental>
  </points>
  <series>1</series>
  <title>Upper critical solution temperatures of the systems nitromethane (1) + Tetradecane (2)</title>
 </dataset>
 <keywords>Solubility, Solubility data series</keywords>
 <method>The synthetic method was used. A Reichert microscope, type RCH, with a heating stage was used. A 26 x 38 mm slide was adapted to hold capillaries on the stage. Two glass strips were glued, using water glass, to the slide, leaving a 0.5 mm channel. The slide was then placed in the adjustable device of the heating stage. (1) and (2) were put into capillary tubing (0.2-0.3 mm diameter) by dipping consecutively into both liquids. The height of the liquid was 7-10 mm. Room temperature solids were melted on a glass slide over a microburner. The capillary was sealed at both ends to a length of 30-35 mm, then inserted in to the channel on the slide and heated on the stage. The UCST was determined by following the appearance and disappearance of the meniscus.</method>
 <publisher>The International Union of Pure and Applied Chemistry</publisher>
 <sources>
  <citation>Schmid, H. H. O.; Mangold, H. K.; Lundberg, W. O.; J. Am. Oil Chem. Soc. 42, 372 (1965).</citation>
  <pubtype>paper</pubtype>
  <url>https://doi.org/10.1007/bf02635572</url>
 </sources>
 <substances>
  <casrn>75-52-5</casrn>
  <constituent>1</constituent>
  <formula>CH3NO2 </formula>
  <inchi>InChI=1S/CH3NO2/c1-2(3)4/h1H3</inchi>
  <inchikey>LYGJENNIWJXYER-UHFFFAOYSA-N</inchikey>
  <molweight>61.04</molweight>
  <name>Nitromethane</name>
  <sample>Fisher Scientific Co.; certified, No. N-98;&lt;br/&gt;$n_{D}^{20}$ = \pu{1.3820}$, $\rho^{20} = \pu{1134 g L-1}$.</sample>
 </substances>
 <substances>
  <casrn>629-59-4</casrn>
  <constituent>2</constituent>
  <formula>C14H30</formula>
  <inchi>InChI=1S/C14H30/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3-14H2,1-2H3</inchi>
  <inchikey>BGHCVCJVXZWKCC-UHFFFAOYSA-N</inchikey>
  <molweight>198.388</molweight>
  <name>Tetradecane</name>
  <sample>Not specified.</sample>
 </substances>
 <system>Nitromethane with Tetradecane</system>
 <title>Solubility data from IUPAC SDS Volume 71 (page 1251) - Nitromethane with Tetradecane</title>
</compilation>