{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page 1249) - Nitromethane with 4-Methyl-2-heptene", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Mulliken, S. P.; Wakeman, R. L.; Recl. Trav. Chim. Pays-Bas, 54, 366-72 (1935).", "pubtype": "paper", "url": "https://doi.org/10.1002/recl.19350540508"}], "system": "Nitromethane with 4-Methyl-2-heptene", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 2, "name": "4-Methyl-2-heptene", "formula": "C8H16", "molweight": 112.21, "casrn": "3404-56-6", "inchi": "InChI=1S/C8H16/c1-4-6-8(3)7-5-2/h4,6,8H,5,7H2,1-3H3", "inchikey": "SVGLFIBXFVQUQY-UHFFFAOYSA-N", "sample": "2-pentene synthesized in the Research Lab of Organic Chemistry Massachusetts Institute of Technology; some alkenes (*) were obtained from Dr. H. E. Buc, Standard Oil Development Co.; the others were the purest commercial samples available from BDH."}], "method": "The synthetic method was used. Miscibility was determined in a glass-stoppered tube of 4 mm inside diameter. Equal volumes (0.1 mL) of (1) and (2) were measured into the tube which was then strapped to a thermometer, warmed to 5 or 10 \u00b0C above the solubility temperature, mixed well by shaking, and then allowed to cool slowly, still shaking, in a bath of white oil (above 30 \u00b0C) or water (below 30 \u00b0C).", "dataset": [{"series": 1, "title": "Solubility temperatures of mixtures with equal volumes of nitromethane (1) + 4-Methyl-2-heptene (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "8.1e+01", "significand": "8.1", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.54e+02", "significand": "3.54", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}, {"property": "Boiling point", "value": "113.8-114.1", "unit": "°C"}], "data": [], "supplemental": []}]}]}}