{"compilation": {"title": "Solubility data from IUPAC SDS Volume 71 (page 1250) - Nitromethane with 4,5-Dimethyl-2,6-octadiene", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Mulliken, S. P.; Wakeman, R. L.; Recl. Trav. Chim. Pays-Bas, 54, 366-72 (1935).", "pubtype": "paper", "url": "https://doi.org/10.1002/recl.19350540508"}], "system": "Nitromethane with 4,5-Dimethyl-2,6-octadiene", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 2, "name": "4,5-Dimethyl-2,6-octadiene", "formula": "C10H18", "molweight": 138.25, "casrn": "18476-57-8", "inchi": "InChI=1S/C10H18/c1-5-7-9(3)10(4)8-6-2/h5-10H,1-4H3", "inchikey": "JASAKDWEYSDIHI-UHFFFAOYSA-N", "sample": "Some alkadienes(*) were obtained from Dr. F. Cortese; others were purest commercial samples available from BDH."}], "method": "The synthetic method was used. Miscibility was determined in a glass-stoppered tube of 4 mm inside diameter. Equal volumes (0.1 mL) of (1) and (2) were measured into the tube which was then strapped to a thermometer, warmed to 5 or 10 \u00b0C above the solubility temperature, mixed well by shaking, and then allowed to cool slowly, still shaking, in a bath of white oil, water or (below 0 \u00b0C) non-freezing mixture.", "dataset": [{"series": 1, "title": "Solubility temperatures of mixtures with equal volumes of nitromethane (1) + 4,5-Dimethyl-2,6-octadiene (2)", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "7.8e+01", "significand": "7.8", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "3.51e+02", "significand": "3.51", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "value": "152.9-153.8", "unit": "°C"}], "data": [], "supplemental": []}]}]}}