{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/306/jsonld#"}], "@id": "", "generatedAt": "08-20-26 05:50:08", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/306/jsonld#", "@type": "sdo:scidataFramework", "uid": "37_176", "title": "Solubility data from IUPAC SDS Volume 37 (page 219) - Methylcyclopentane with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Marie C. Haulait-Pirson", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:reference", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The equilibrium distribution was attained after shaking for 10 min the thermostatted reactor containing (2) and the (1) vapor. After being allowed to stand for 10 min, equal calibrated volumes of samples of the gas and solution were introduced by a syringe into a special cell for the removal of (1) by blowing, built into the gas line of the chromatograph and the partition coefficient \u03b1 was determined as the ratio of the areas of the peaks of the substrate arising from the two phases.", "references": [{"@id": "procedure/1/reference/1/", "@type": "sdo:reference", "number": 1, "citation": "Hine, J.; Mooker, P. K.; J. Org. Chem. 1975, 4, 292.", "doi": "10.1021/jo00891a006", "url": "https://doi.org/10.1021/jo00891a006"}]}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Methylcyclopentane", "formula": "C6H12", "casrn": "96-37-7", "iupacname": "methylcyclopentane", "inchikey": "GDOPTJXRTPNYNR-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Methylcyclopentane", "description": "Not specified.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "not specified.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Methylcyclopentane with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Rudakov, E. S.; Lutsyk, A. I.; Zh. Fiz. Khim. 1979, 53, 1298-1300."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 37 (page 219) - Methylcyclopentane with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-37.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}