{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/247/jsonld#"}], "@id": "", "generatedAt": "08-20-26 16:01:00", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/247/jsonld#", "@type": "sdo:scidataFramework", "uid": "37_122", "title": "Solubility data from IUPAC SDS Volume 37 (page 160) - Benzene with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Andrzej Maczynski", "role": "compiler"}, {"@id": "author/2/", "@type": "dc:creator", "name": "Z. Maczynska", "role": "compiler"}, {"@id": "author/3/", "@type": "dc:creator", "name": "A. Szafranski", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:constituent", "sdo:methodology", "sdo:mixture", "sdo:procedure", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "w3i:Chemistry", "w3i:PhysicalChemistry"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "A mixture of (1) and (2) was equilibrated at 25 \u00b1 0.1 \u00b0C for a minimum of 12 hrs in a 200-mL Teflon-stoppered vessel (25 cm long and 3.5 cm across) with gentle shaking, allowed to settle for 6 hrs and tested for the absence of emulsion (Tyndall effect). The aqueous and organic phases were analyzed by GLC with internal standardization) on a Hewlett-Packard Model 700 instrument equipped with a 15% SE-30 on 60/80 mesh acid-washed $\\ce{(CH3)2Cl2Si}$-treated Chromosorb P column (steel capillary 10 ft x 0.125 inch). The (1) in the aqueous phase was extracted into 5 mL of heptane and the extract analyzed by glc.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Benzene", "formula": "C6H6", "casrn": "71-43-2", "iupacname": "benzene", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Benzene", "description": "Phillip Petroleum Co. research grade, 99+ mole%; used as received.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "doubly distilled", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Benzene with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Leinonen, P. J.; Mackay, D.; Can. J. Chem. Eng. 1973, 51, 230-3.", "doi": "10.1002/cjce.5450510213", "url": "https://doi.org/10.1002/cjce.5450510213"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 37 (page 160) - Benzene with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-37.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}