{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 160) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska, A. Szafranski", "sources": [{"citation": "Leinonen, P. J.; Mackay, D.; Can. J. Chem. Eng. 1973, 51, 230-3.", "pubtype": "paper", "url": "https://doi.org/10.1002/cjce.5450510213"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "doubly distilled"}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Phillip Petroleum Co. research grade, 99+ mole%; used as received."}], "method": "A mixture of (1) and (2) was equilibrated at 25 \u00b1 0.1 \u00b0C for a minimum of 12 hrs in a 200-mL Teflon-stoppered vessel (25 cm long and 3.5 cm across) with gentle shaking, allowed to settle for 6 hrs and tested for the absence of emulsion (Tyndall effect). The aqueous and organic phases were analyzed by GLC with internal standardization) on a Hewlett-Packard Model 700 instrument equipped with a 15% SE-30 on 60/80 mesh acid-washed $\\ce{(CH3)2Cl2Si}$-treated Chromosorb P column (steel capillary 10 ft x 0.125 inch). The (1) in the aqueous phase was extracted into 5 mL of heptane and the extract analyzed by glc.", "dataset": []}}