{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 134) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska, A. Szafranski", "sources": [{"citation": "Jones, J. R.; Monk, C. B.; J. Chem. Soc. 1963, 2633-5.", "pubtype": "paper", "url": "https://doi.org/10.1039/jr9630002633"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "\"Analar\" grade; repurified by conventional methods [1]."}], "method": "In a thermostatted glass stoppered flask 10-25 mL (1) was shaken for min four hours. with tritiated water (a few mL of $\\ce{HTO}$ equivalent to ca. 2 mCi/mL) and decanted. A 5-mL aliquot was re-shaken for four hours. with 5 mL $\\ce{H2O}$ in a 10 mL flask, sampled and assayed with a Nuclear Enterprises type 8301 liquid scintillation counter. The two-stage process eliminates quenching effects (due to solvent) on the scintillator.", "reference": {"citation": "Vogel 'Practical Organic Chemistry' Longmans, Green and Co., London, 1956.", "pubtype": "book"}, "dataset": [{"series": 1, "title": "Solubility of water in benzene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Solubility (v/v) (2 in 1)", "number": "5.7e-04", "significand": "5.7", "exponent": "-4", "sigfigs": "2", "unit": "$\\pu{cm3(\\rm{2})/cm3(\\rm{1})}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Solubility (v/v) (2 in 1)", "number": "6.5e-04", "significand": "6.5", "exponent": "-4", "sigfigs": "2", "unit": "$\\pu{cm3(\\rm{2})/cm3(\\rm{1})}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.5e+01", "significand": "3.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Solubility (v/v) (2 in 1)", "number": "7.5e-04", "significand": "7.5", "exponent": "-4", "sigfigs": "2", "unit": "$\\pu{cm3(\\rm{2})/cm3(\\rm{1})}$"}], "supplemental": []}]}]}}