{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/214/jsonld#"}], "@id": "", "generatedAt": "08-18-26 13:22:42", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/214/jsonld#", "@type": "sdo:scidataFramework", "uid": "20_93", "title": "Solubility data from IUPAC SDS Volume 20 (page 107) - 1,4-Dichlorobenzene with Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "A. Vesala", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:stringvalue", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "afrl:0000270", "obo:NCIT_C25206", "qudt:DEG_C", "sdo:numericvalue", "sdo:stringvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float", "xsd:str"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The equilibrations were done over periods from 2 to 1seven days (average 7-10 days). Gravimetric analysis was the basis for the concentration determinations. The solute was placed in a spiral tube and weighed. Then, a known amount of water was passed through the tube and it was re-weighed. The weight loss and the mass of the water passed through the tube gave the solubility value directly.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "1,4-Dichlorobenzene", "formula": "C6H4Cl2", "casrn": "106-46-7", "iupacname": "1,4-dichlorobenzene", "inchikey": "OCJBOOLMMGQPQU-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "1,4-Dichlorobenzene", "description": "Synthesized from benzene and chlorine, recrystallized from abs. ethanol, MP = 53°C. The purity of the product was checked by elemental analysis.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Water", "description": "Source and purity not specified.", "substance#": "substance/2/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "1,4-Dichlorobenzene with Water", "type": "binary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solute", "role#": "afrl:0000270"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Degree celsius", "unit#": "qudt:DEG_C"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.0e+01", "significand": 2.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.5e+01", "significand": 2.5, "exponent": 1, "sigfigs": 2}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.0e+01", "significand": 3.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.5e+01", "significand": 3.5, "exponent": 1, "sigfigs": 2}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "4.0e+01", "significand": 4.0, "exponent": 1, "sigfigs": 2}, {"@id": "condition/6/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "4.5e+01", "significand": 4.5, "exponent": 1, "sigfigs": 2}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "20:093:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.444e-06", "significand": 8.444, "exponent": -6, "sigfigs": 4}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.89e-02", "significand": 6.89, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.687e-04", "significand": 4.687, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "20:093:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.694e-06", "significand": 9.694, "exponent": -6, "sigfigs": 4}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7.91e-02", "significand": 7.91, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.380e-04", "significand": 5.38, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "20:093:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.104e-05", "significand": 1.104, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.33e-02", "significand": 9.33, "exponent": -2, "sigfigs": 3}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.346e-04", "significand": 6.346, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "20:093:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "12.75,10.17 x E-6"}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "10.4,8.30 x E-2"}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:stringvalue", "datatype": "xsd:str", "text": "7.074,5.646"}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "20:093:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.238e-05", "significand": 1.238, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.01e-01", "significand": 1.01, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.870e-04", "significand": 6.87, "exponent": -4, "sigfigs": 4}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "20:093:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.495e-05", "significand": 1.495, "exponent": -5, "sigfigs": 4}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Relative mass - solution (1)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.22e-01", "significand": 1.22, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Molality (1 in 2)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.298e-04", "significand": 8.298, "exponent": -4, "sigfigs": 4}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Klemenc, A.; L\u00f6w, M.; Rec. Trav. Chim. Pays-Bas 1930, 49(4), 629-40.", "doi": "10.1002/recl.19300490705", "url": "https://doi.org/10.1002/recl.19300490705"}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 20 (page 107) - 1,4-Dichlorobenzene with Water", "url": "https://iupac.github.io/SolubilityDataSeries/volumes/SDS-20.pdf"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}