{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 125) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Constantine Tsonopoulos, Glenn T. Hefter", "sources": [{"citation": "Pavia, R. A.; \"The Solubility of Water in Benzene\", M.S. Thesis, 1958, North Carolina State College, Raleigh, NC.", "pubtype": "thesis"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Allied Chemical: purified by triple fractional crystallization; purity 99.99 mol%; $n_{0}^{25}$ = 1.49806."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Distilled in a tinned Barnstead still (specific conductivity $\\pu{5-20E-7 ohm-1}$"}], "method": "Water and benzene were equilibrated in a 4-L pyrex vessel fitted with a stirrer. Equilibration typically required about 100 h of stirring. Care was taken to avoid condensation of water on the vessel lid and selective absorption of water on the glass walls. Samples of analysis were withdrawn by air pressure. Water was determined by Karl Fischer titration.", "dataset": [{"series": 1, "title": "Solubility of water in benzene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "9.28e+00", "significand": "9.28", "exponent": "0", "sigfigs": "3", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "8.774e+00", "significand": "8.774", "exponent": "0", "sigfigs": "4", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "1.783e-03", "significand": "1.783", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.783e-03", "significand": "1.783", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "4.117e-02", "significand": "4.117", "exponent": "-2", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.000e+01", "significand": "2.000", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "1.7535e+01", "significand": "1.7535", "exponent": "1", "sigfigs": "5", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "2.592e-03", "significand": "2.592", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.592e-03", "significand": "2.592", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "5.989e-02", "significand": "5.989", "exponent": "-2", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.000e+01", "significand": "2.000", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "1.7535e+01", "significand": "1.7535", "exponent": "1", "sigfigs": "5", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "2.629e-03", "significand": "2.629", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.629e-03", "significand": "2.629", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "6.076e-02", "significand": "6.076", "exponent": "-2", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.017e+01", "significand": "3.017", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "3.2136e+01", "significand": "3.2136", "exponent": "1", "sigfigs": "5", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "3.597e-03", "significand": "3.597", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.597e-03", "significand": "3.597", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "8.318e-02", "significand": "8.318", "exponent": "-2", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "4.015e+01", "significand": "4.015", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "5.5764e+01", "significand": "5.5764", "exponent": "1", "sigfigs": "5", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "4.845e-03", "significand": "4.845", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "4.845e-03", "significand": "4.845", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "1.1216e-01", "significand": "1.1216", "exponent": "-1", "sigfigs": "5", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "4.997e+01", "significand": "4.997", "exponent": "1", "sigfigs": "4", "unit": "&deg;C"}, {"property": "Ambient pressure", "number": "9.237e+01", "significand": "9.237", "exponent": "1", "sigfigs": "4", "unit": "mm Hg"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "6.567e-03", "significand": "6.567", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "6.567e-03", "significand": "6.567", "exponent": "-3", "sigfigs": "4", "unit": "1"}], "supplemental": [{"property": "Relative mass - 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