{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 94) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Uspenskii, S. P.; Neft. Khoz. 1929, 11-12, 713-7.", "pubtype": "paper", "url": "https://oil-industry.net/pdf/1929/12/713_uspensky.pdf"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not specified."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Source not specified; BP = 79.8&deg;C at 740 mm Hg, $d_{4}^{22}$ = 0.8768, $d_{4}^{10}$ = 0.8887."}], "method": "The solubility of (1) in (2) was determined by titration. The solubility of (2) in (1) was determined by Clifford's method [1]. Dried air was passed through the vessel with a saturated solution of (2) in (1) and U-tubes with $\\ce{CaCl2}$ and next absorbed (2) was weighed.", "reference": {"citation": "Clifford, C. W.; Ind. Eng. Chem. 1921, 13, 628.", "pubtype": "paper", "url": "https://doi.org/10.1021/ie50139a018"}, "dataset": [{"series": 1, "title": "Solubility of benzene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "1.75e-01", "significand": "1.75", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.04e-04", "significand": "4.04", "exponent": "-4", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.2e+01", "significand": "2.2", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "1.865e-01", "significand": "1.865", "exponent": "-1", "sigfigs": "4", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.306e-04", "significand": "4.306", "exponent": "-4", "sigfigs": "4", "unit": "1"}]}]}, {"series": 2, "title": "Solubility of water in benzene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.0e+01", "significand": "1.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "5.1e-02", "significand": "5.1", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "2.2e-03", "significand": "2.2", "exponent": "-3", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.2e+01", "significand": "2.2", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "6.62e-02", "significand": "6.62", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "2.86e-03", "significand": "2.86", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}]}]}}