{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 121) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, Z. Maczynska", "sources": [{"citation": "Wing, J.; Johnston, W. H.; J. Am. Chem. Soc. 1957, 79(4), 864-5.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01561a021"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Tracerlab, Inc., tritiated water with an activity of approximately 1 microCi/mL."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "source not specified, chemical grade; redistilled in a column of 50 theoretical plates; purity not specified."}], "method": "A small amount of (2) was equilibrated with 20 mL of (1) using a Teflon stirrer in a 100 mL flask in a Sargent constant temperature bath. At the end of two hours, the mixture was poured into a test tube immersed in the bath and the organic phase separated from water by gravitation. The determination of $\\ce{THO}$ in the organic phase was done by isotopic dilution with a large excess of $\\ce{H2O}$. The tritium activities in the tritiated water samples were determined by the acetylene method described in [1].", "reference": {"citation": "Wing, J.; Johnston, W. H.; Science 1955, 121, 674-5.", "pubtype": "paper", "url": "https://doi.org/10.1126/science.121.3149.674"}, "dataset": []}}