{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 176) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski, A. Szafranski", "sources": [{"citation": "Bittrich, H.-J.; Gedan, H.; Feix, G.; Z. Phys. Chem. 1979, 260 1009-13.", "pubtype": "paper", "url": "https://doi.org/10.1515/zpch-1979-260128"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "not specified."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "source not specified; distilled and recrystallized; glc pure."}], "method": "A mixture of (1) and (2) was shaken at a specified temperature and then thermostatted for 48 h. The equilibrated phases were sampled and analyzed by flame-ionization GLC using 3-m steel columns of 10% SE 30-on-Chromaton N (90 \u00b0C) and 1.5 g + 10% SE 30-on-Chromaton N (120 \u00b0C) for (1) and (2), respectively.", "dataset": [{"series": 1, "title": "Solubility of benzene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "1.79e+03", "significand": "1.79", "exponent": "3", "sigfigs": "3", "unit": "mg/kg"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.133e-04", "significand": "4.133", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.790e-01", "significand": "1.790", "exponent": "-1", "sigfigs": "4", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "2.025e+03", "significand": "2.025", "exponent": "3", "sigfigs": "4", "unit": "mg/kg"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.676e-04", "significand": "4.676", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "2.025e-01", "significand": "2.025", "exponent": "-1", "sigfigs": "4", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "6.0e+01", "significand": "6.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (1)", "number": "2.442e+03", "significand": "2.442", "exponent": "3", "sigfigs": "4", "unit": "mg/kg"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "5.641e-04", "significand": "5.641", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "2.442e-01", "significand": "2.442", "exponent": "-1", "sigfigs": "4", "unit": "g<sub>1</sub>/100 g sln"}]}]}, {"series": 2, "title": "Solubility of water in benzene", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "5.86e+02", "significand": "5.86", "exponent": "2", "sigfigs": "3", "unit": "mg/kg"}, {"property": "Relative mass - solution (2)", "number": "5.86e-02", "significand": "5.86", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "2.54e-03", "significand": "2.54", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "7.12e+02", "significand": "7.12", "exponent": "2", "sigfigs": "3", "unit": "mg/kg"}, {"property": "Relative mass - solution (2)", "number": "7.12e-02", "significand": "7.12", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "3.08e-03", "significand": "3.08", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "6.0e+01", "significand": "6.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Relative mass - solution (2)", "number": "8.6e+02", "significand": "8.6", "exponent": "2", "sigfigs": "2", "unit": "mg/kg"}, {"property": "Relative mass - solution (2)", "number": "8.60e-02", "significand": "8.60", "exponent": "-2", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}], "supplemental": [{"property": "Mole fraction - Liquid (2)", "number": "3.72e-03", "significand": "3.72", "exponent": "-3", "sigfigs": "3", "unit": "1"}]}]}]}}