{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 54) - Pentane with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Marie C. Haulait-Pirson", "sources": [{"citation": "Nelson, H. D.; De Ligny, C. L.; Recl. Trav. Chim. Pays-Bas 1968, 87, 528-44.", "pubtype": "paper", "url": "https://doi.org/10.1002/recl.19680870505"}], "system": "Pentane with Water", "substances": [{"constituent": 1, "name": "Pentane", "formula": "C5H12", "molweight": 72.1488, "casrn": "109-66-0", "inchi": "InChI=1S/C5H12/c1-3-5-4-2/h3-5H2,1-2H3", "inchikey": "OFBQJSOFQDEBGM-UHFFFAOYSA-N", "sample": "Phillips pure grade."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Tap-water was refluxed for eight hours in the presence of $\\ce{KMnO4}$ and $\\ce{KOH}$ and distilled. The whole process was repeated once more."}], "method": "The saturation vessel is drawn in the original paper. (2) was saturated with (1) via the vapor phase: a few drops of (1) were put on the bottom of a tight-fitting flask containing a small flask filled with water. Complete saturation was reached by shaking overnight in an upright position. Samples were taken from the aqueous solution with a microsyringe through the septum and injected into the gas chromatograph detector. The gas chromatographic conditions are described in the paper.", "dataset": [{"series": 1, "title": "Solubility of pentane in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "4.0e+00", "significand": "4.0", "exponent": "0", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.02e-05", "significand": "1.02", "exponent": "-5", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "4.09e-02", "significand": "4.09", "exponent": "-2", "sigfigs": "3", "unit": "g/kg"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.00e+01", "significand": "1.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.07e-05", "significand": "1.07", "exponent": "-5", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "4.29e-02", "significand": "4.29", "exponent": "-2", "sigfigs": "3", "unit": "g/kg"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.00e+01", "significand": "2.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "9.8e-06", "significand": "9.8", "exponent": "-6", "sigfigs": "2", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "3.93e-02", "significand": "3.93", "exponent": "-2", "sigfigs": "3", "unit": "g/kg"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.01e-05", "significand": "1.01", "exponent": "-5", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "4.05e-02", "significand": "4.05", "exponent": "-2", "sigfigs": "3", "unit": "g/kg"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.00e+01", "significand": "3.00", "exponent": "1", "sigfigs": "3", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.01e-05", "significand": "1.01", "exponent": "-5", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (1)", "number": "4.05e-02", "significand": "4.05", "exponent": "-2", "sigfigs": "3", "unit": "g/kg"}]}]}]}}