{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 182) - Chlorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Gabor Jancso", "sources": [{"citation": "Hutchinson, C. A.; Lyon, A. M.; Columbia University Report A-745, July 1, 1943.", "pubtype": "report"}], "system": "Chlorobenzene with Water", "substances": [{"constituent": 1, "name": "Chlorobenzene", "formula": "C6H5C1", "molweight": 112.557, "casrn": "108-90-7", "inchi": "InChI=1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "MVPPADPHJFYWMZ-UHFFFAOYSA-N", "sample": "Chlorobenzene was carefully purified and dried before use. Source and method not given."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Source not specified."}], "method": "Between 25 and 100 mL of chlorobenzene and 1 to 2 mL $\\ce{D2O}$ were introduced into a flask and shaken for about 90 min. The water bath temperature was maintained within \u00b10.05 \u00b0C. Then, a sample was taken and the dissolved $\\ce{D2O}$ content was determined by a modified Karl Fischer titration as described in [1]. The original report was unavailable, but the method and the results have been described in sufficient detail in [1]. The solubility of $\\ce{H2O}$ in chlorobenzene was also determined and found to be 0.00250 \u00b1 0.00003 mol $\\ce{H2O}$/ 100 g solution from three separate experiments.", "reference": {"citation": "Eidinoff, M. L. In \"Production of Heavy Water\", National Nuclear Energy Series Division III-Vol. 4F, Murphy, G. M.; Urey, H. C.; Kirshenbaum, I.; Eds.; McGraw-Hill: New York, 1955; Part II, Chapter 7, pp 129-44.", "pubtype": "chapter"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.460e-03", "significand": "2.460", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.386e-01", "significand": "4.386", "exponent": "-1", "sigfigs": "4", "unit": "g/kg"}, {"property": "Molality (1)", "number": "2.19e-02", "significand": "2.19", "exponent": "-2", "sigfigs": "3", "unit": "mol/kg"}], "supplemental": []}]}]}}