{"compilation": {"title": "Solubility data from IUPAC SDS Volume 20 (page 175) - Chlorobenzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Ari L. Horvath", "sources": [{"citation": "Vesala, A.; Ph.D. Dissertation, University of Turku, Turku, 1973.", "pubtype": "dissertation"}], "system": "Chlorobenzene with Water", "substances": [{"constituent": 1, "name": "Chlorobenzene", "formula": "C6H5C1", "molweight": 112.557, "casrn": "108-90-7", "inchi": "InChI=1S/C6H5Cl/c7-6-4-2-1-3-5-6/h1-5H", "inchikey": "MVPPADPHJFYWMZ-UHFFFAOYSA-N", "sample": "Merck AG., >99% GLC, used as received."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled, deionized, and degassed."}], "method": "The solute was equilibrated with water by stirring in a sealed flask [1] with a magnetic stirrer for 48 hours at constant temperature. A sample was withdrawn and filtered through a glass-wool plug and the solute was extracted with 2,2,4-trimethylpentene. The optical densities were determined spectrophotometrically [2]. The mean and standard deviation were obtained from eight independent measurements.", "reference": {"citation": "Wauchope, R. D.; Getzen, F. W.; J. Chem. Eng. Data 1972, 17(1), 38-41.", "pubtype": "paper", "url": "https://doi.org/10.1021/je60052a020"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "7.4004e-05", "significand": "7.4004", "exponent": "-5", "sigfigs": "5", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.622e-01", "significand": "4.622", "exponent": "-1", "sigfigs": "4", "unit": "g/kg"}, {"property": "Molality (1 in 2)", "number": "4.108e-03", "significand": "4.108", "exponent": "-3", "sigfigs": "4", "unit": "mol/kg"}], "supplemental": []}]}]}}