{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 111) - Benzene with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Glenn T. Hefter", "sources": [{"citation": "Bohon, R. L.; Claussen, W. F.; J. Am. Chem. Soc. 1951, 73, 1571-8.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01148a047"}], "system": "Benzene with Water", "substances": [{"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Air-free conductivity water, no other details given."}, {"constituent": 1, "name": "Benzene", "formula": "C6H6", "molweight": 78.1118, "casrn": "71-43-2", "inchi": "InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H", "inchikey": "UHOVQNZJYSORNB-UHFFFAOYSA-N", "sample": "Baker and Adamson, purified by recrystallization from ethanol, washing, filtering through silica gel then distilling. Purity was determined by refractometry (no values given)."}], "method": "A round-bottmed flask containing about 4 mL of (1) and 400 mL of (2) was evacuated, suspended in a thermostat, shaken for 24h and then allowed to settle for at least another 24h. Next, desired quantities of the water layer were syphoned into 6 glass-stoppered Erlenmeyer flasks. These 6 flasks had previously been tared, partially filled with a suitable amount of diluent water, and reweighed. Weighed portions of the samples were inserted into a quartz cuvette and measured in a Beckman DU spectrophotometer. Absorbances were corrected for absorption of (1) onto the walls of the cuvette.", "dataset": [{"series": 1, "title": "Solubility of benzene in water", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "4e-01", "significand": "4", "exponent": "-1", "sigfigs": "1", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.01e-04", "significand": "4.01", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.74e-01", "significand": "1.74", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "5.2e+00", "significand": "5.2", "exponent": "0", "sigfigs": "2", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.17e-04", "significand": "4.17", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.81e-01", "significand": "1.81", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "1.00e+01", "significand": "1.00", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.15e-04", "significand": "4.15", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.80e-01", "significand": "1.80", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "1.49e+01", "significand": "1.49", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.10e-04", "significand": "4.10", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.78e-01", "significand": "1.78", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "2.10e+01", "significand": "2.10", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.13e-04", "significand": "4.13", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.79e-01", "significand": "1.79", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "2.50e+01", "significand": "2.50", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.13e-04", "significand": "4.13", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.79e-01", "significand": "1.79", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "2.56e+01", "significand": "2.56", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.13e-04", "significand": "4.13", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.79e-01", "significand": "1.79", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "3.02e+01", "significand": "3.02", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.24e-04", "significand": "4.24", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.84e-01", "significand": "1.84", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "3.49e+01", "significand": "3.49", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.36e-04", "significand": "4.36", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "1.89e-01", "significand": "1.89", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}, {"pntnum": 10, "conditions": [{"property": "Ambient temperature", "number": "4.28e+01", "significand": "4.28", "exponent": "1", "sigfigs": "3", "unit": "&deg;C"}], "data": [], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.61e-04", "significand": "4.61", "exponent": "-4", "sigfigs": "3", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "2.00e-01", "significand": "2.00", "exponent": "-1", "sigfigs": "3", "unit": "g<sub>1</sub>/100 g sln"}]}]}]}}