A. Vesala 0 -8.2e+00 Ambient temperature 2 -8.2 °C -1 6.2357e-01 Mole fraction - Liquid (1) 5 6.2357 1 2 9.220e+02 Relative mass - solution (1) 4 9.220 g/kg 0 7.1719e+00 Molality (1 in 2) 5 7.1719 mol/kg 1 0 -8.0e+00 Ambient temperature 2 -8.0 °C -1 5.8243e-01 Mole fraction - Liquid (1) 5 5.8243 1 2 9.087e+02 Relative mass - solution (1) 4 9.087 g/kg 0 7.0685e+00 Molality (1 in 2) 5 7.0685 mol/kg 2 0 -6.0e+00 Ambient temperature 2 -6.0 °C -1 6.8440e-01 Mole fraction - Liquid (1) 5 6.8440 1 2 9.393e+02 Relative mass - solution (1) 4 9.393 g/kg 0 7.3065e+00 Molality (1 in 2) 5 7.3065 mol/kg 3 0 -5.0e+00 Ambient temperature 2 -5.0 °C -1 5.4750e-01 Mole fraction - Liquid (1) 5 5.4750 1 2 8.962e+02 Relative mass - solution (1) 4 8.962 g/kg 0 6.9712e+00 Molality (1 in 2) 5 6.9712 mol/kg 4 0 -4.0e+00 Ambient temperature 2 -4.0 °C -1 5.3778e-01 Mole fraction - Liquid (1) 5 5.3778 1 2 8.925e+02 Relative mass - solution (1) 4 8.925 g/kg 0 6.9424e+00 Molality (1 in 2) 5 6.9424 mol/kg 5 0 -2.0e+00 Ambient temperature 2 -2.0 °C -1 5.0050e-01 Mole fraction - Liquid (1) 5 5.0050 1 2 8.773e+02 Relative mass - solution (1) 4 8.773 g/kg 0 6.8242e+00 Molality (1 in 2) 5 6.8242 mol/kg 6 0 -1.5e+00 Ambient temperature 2 -1.5 °C -1 8.0714e-01 Mole fraction - Liquid (1) 5 8.0714 1 2 9.676e+02 Relative mass - solution (1) 4 9.676 g/kg 0 7.5266e+00 Molality (1 in 2) 5 7.5266 mol/kg 7 -1 -3.0e-01 Ambient temperature 2 -3.0 °C -3 3.493e-03 Mole fraction - Liquid (1) 4 3.493 1 1 2.44e+01 Relative mass - solution (1) 3 2.44 g/kg -1 1.898e-01 Molality (1 in 2) 4 1.898 mol/kg 8 -1 -2.0e-01 Ambient temperature 2 -2.0 °C -3 2.216e-03 Mole fraction - Liquid (1) 4 2.216 1 1 1.56e+01 Relative mass - solution (1) 3 1.56 g/kg -1 1.213e-01 Molality (1 in 2) 4 1.213 mol/kg 9 0 2.0e+00 Ambient temperature 2 2.0 °C -1 8.9544e-01 Mole fraction - Liquid (1) 5 8.9544 1 2 9.839e+02 Relative mass - solution (1) 4 9.839 g/kg 0 7.6534e+00 Molality (1 in 2) 5 7.6534 mol/kg 10 0 7.0e+00 Ambient temperature 2 7.0 °C 0 1.0e+00 Mole fraction - Liquid (1) 2 1.0 1 3 1.0000e+03 Relative mass - solution (1) 5 1.0000 g/kg 0 7.7787e+00 Molality (1 in 2) 5 7.7787 mol/kg 11 1 8.29e+01 Ambient temperature 3 8.29 °C -3 5.445e-03 Mole fraction - Liquid (1) 4 5.445 1 1 3.76e+01 Relative mass - solution (1) 3 3.76 g/kg -1 2.925e-01 Molality (1 in 2) 4 2.925 mol/kg 12 1 9.15e+01 Ambient temperature 3 9.15 °C -1 4.6056e-01 Mole fraction - Liquid (1) 5 4.6056 1 2 8.590e+02 Relative mass - solution (1) 4 8.590 g/kg 0 6.6819e+00 Molality (1 in 2) 5 6.6819 mol/kg 13 2 1.063e+02 Ambient temperature 4 1.063 °C -3 7.506e-03 Mole fraction - Liquid (1) 4 7.506 1 1 5.12e+01 Relative mass - solution (1) 3 5.12 g/kg -1 3.983e-01 Molality (1 in 2) 4 3.983 mol/kg 14 2 1.189e+02 Ambient temperature 4 1.189 °C -1 4.0319e-01 Mole fraction - Liquid (1) 5 4.0319 1 2 8.282e+02 Relative mass - solution (1) 4 8.282 g/kg 0 6.4423e+00 Molality (1 in 2) 5 6.4423 mol/kg 15 2 1.566e+02 Ambient temperature 4 1.566 °C -1 2.5197e-01 Mole fraction - Liquid (1) 5 2.5197 1 2 7.062e+02 Relative mass - solution (1) 4 7.062 g/kg 0 5.433e+00 Molality (1 in 2) 4 5.433 mol/kg 16 2 1.591e+02 Ambient temperature 4 1.591 °C -2 2.1547e-02 Mole fraction - Liquid (1) 5 2.1547 1 2 1.358e+02 Relative mass - solution (1) 4 1.358 g/kg 0 1.0563e+00 Molality (1 in 2) 5 1.0563 mol/kg 17 2 1.658e+02 Ambient temperature 4 1.658 °C -2 2.7806e-02 Mole fraction - Liquid (1) 5 2.7806 1 2 1.695e+02 Relative mass - solution (1) 4 1.695 g/kg 0 1.3185e+00 Molality (1 in 2) 5 1.3185 mol/kg 18 2 1.662e+02 Ambient temperature 4 1.662 °C -1 1.7806e-01 Mole fraction - Liquid (1) 5 1.7806 1 2 6.072e+02 Relative mass - solution (1) 4 6.072 g/kg 0 4.7232e+00 Molality (1 in 2) 5 4.7232 mol/kg 19 2 1.701e+02 Ambient temperature 4 1.701 °C -1 1.4598e-01 Mole fraction - Liquid (1) 5 1.4598 1 2 5.495e+02 Relative mass - solution (1) 4 5.495 g/kg 0 4.2744e+00 Molality (1 in 2) 5 4.2744 mol/kg 20 2 1.707e+02 Ambient temperature 4 1.707 °C -2 3.9289e-02 Mole fraction - Liquid (1) 5 3.9289 1 2 2.259e+02 Relative mass - solution (1) 4 2.259 g/kg 0 1.7572e+00 Molality (1 in 2) 5 1.7572 mol/kg 21 2 1.729e+02 Ambient temperature 4 1.729 °C -1 1.0301e-01 Mole fraction - Liquid (1) 5 1.0301 1 2 4.504e+02 Relative mass - solution (1) 4 4.504 g/kg 0 3.5035e+00 Molality (1 in 2) 5 3.5035 mol/kg 22 2 1.730e+02 Ambient temperature 4 1.730 °C -2 6.4568e-02 Mole fraction - Liquid (1) 5 6.4568 1 2 3.300e+02 Relative mass - solution (1) 4 3.300 g/kg 0 2.5670e+00 Molality (1 in 2) 5 2.5670 mol/kg 23 1 Solubility, Solubility data series The solubility versus temperature measurements were made by the so called synethetic method which involved the mixing of known masses of solute and solvent and the testing of miscibility with temperature. A bracketing procedure was applied in this method, two adjustable thermostats, one above and the other below the solubility temperature, were used. The contents of sample tubes in the two thermostat baths were observed to maintain one homogeneous and the other heterogeneous as the temperature interval between the two thermostats were reduced by successive steps. The International Union of Pure and Applied Chemistry Wohllenben, W. J. Ber. Dtsch. Chem. Ges. 1909, 42, 4370. paper https://doi.org/10.1002/cber.19090420426 Sidgwick, N. V.; Turner, S. L.; J. Chem. Soc. 1922, 121, Part II, 2256-63. paper https://doi.org/10.1039/ct9222102256 7732-18-5 2 H2O InChI=1S/H2O/h1H2 XLYOFNOQVPJJNP-UHFFFAOYSA-N 18.0153 Water Source and purity not specified. 95-57-8 1 C6H5ClO InChI=1S/C6H5ClO/c7-5-3-1-2-4-6(5)8/h1-4,8H ISPYQTSUDJAMAB-UHFFFAOYSA-N 128.556 2-Chlorophenol Synthesized by the chlorination of phenol in carbon tetrachloride, purified as described in [1], no criterions of the purity given. 2-Chlorophenol with Water