{"compilation": {"title": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with Octanoic acid and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov, Nikolai V. Sazonov", "sources": [{"citation": "Sazonov, V. P.; Zh. Fiz. Khim. 45, 473-4 (1971).", "pubtype": "paper"}], "system": "Nitromethane with Octanoic acid and Water", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; pure grade reagent; dried and repeatedly distilled in a packed glass column; $n_{D}^{20}$ = 1.3819, $d_{4}^{20}$ = 1.1380."}, {"constituent": 2, "name": "Octanoic acid", "formula": "C8H16O2", "molweight": 144.211, "casrn": "124-07-2", "inchi": "InChI=1S/C8H16O2/c1-2-3-4-5-6-7-8(9)10/h2-7H2,1H3,(H,9,10)", "inchikey": "WWZKQHOCKIZLMA-UHFFFAOYSA-N", "sample": "Source not specified; pure grade reagent; dried and repeatedly distilled at vacuum; $n_{D}^{20}$ = 1.4279, $d_{4}^{20}$ = 0.9090."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Twice distilled."}], "method": "The synthetic method (Alekseev [1]) was used. Ampoules with given amount of (1), (2) and (3) were heated with vigorous stirring to a temperature somewhat higher than the phase transition temperature and then were slowly cooled till turbidity appeared. Then the turbidity disappearance temperature was determined when heated at a slow rate.", "reference": {"citation": "Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876).", "pubtype": "paper"}, "dataset": [{"series": 3, "title": "Table 3. Composition of three coexisting liquid phases system nitromethane + octanoic acid + water*", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "9e+00", "significand": "9", "exponent": "0", "sigfigs": "1", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.82e+02", "significand": "2.82", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "6.62e-01", "significand": "6.62", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "2.59e-01", "significand": "2.59", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "6.37e-01", "significand": "6.37", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1.06e-01", "significand": "1.06", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "9e+00", "significand": "9", "exponent": "0", "sigfigs": "1", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.82e+02", "significand": "2.82", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "4.46e-01", "significand": "4.46", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "4.82e-01", "significand": "4.82", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "4.99e-01", "significand": "4.99", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.28e-01", "significand": "2.28", "exponent": "-1", "sigfigs": "3", "unit": "1"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "9e+00", "significand": "9", "exponent": "0", "sigfigs": "1", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.82e+02", "significand": "2.82", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "3.2e-02", "significand": "3.2", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mass fraction (2)", "number": "1e-03", "significand": "1", "exponent": "-3", "sigfigs": "1", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "9.7e-03", "significand": "9.7", "exponent": "-3", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "1e-04", "significand": "1", "exponent": "-4", "sigfigs": "1", "unit": "1"}]}]}, {"series": 2, "title": "Table 2. 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