Valerii P. Sazonov 1 3.782e+01 Ambient temperature 4 3.782 °C 2 3.1097e+02 Ambient temperature 5 3.1097 $\pu{K}$ -1 4.874e-01 Mass fraction (1) 4 4.874 1 -1 2.502e-01 Mass fraction (2) 4 2.502 1 1 -1 5.849e-01 Mole fraction - Liquid (1) 4 5.849 1 -1 1.054e-01 Mole fraction - Liquid (2) 4 1.054 1 1 3.787e+01 Ambient temperature 4 3.787 °C 2 3.1102e+02 Ambient temperature 5 3.1102 $\pu{K}$ -1 5.176e-01 Mass fraction (1) 4 5.176 1 -1 2.037e-01 Mass fraction (2) 4 2.037 1 2 -1 5.996e-01 Mole fraction - Liquid (1) 4 5.996 1 -2 8.29e-02 Mole fraction - Liquid (2) 3 8.29 1 1 3.812e+01 Ambient temperature 4 3.812 °C 2 3.1127e+02 Ambient temperature 5 3.1127 $\pu{K}$ -1 5.486e-01 Mass fraction (1) 4 5.486 1 -1 1.560e-01 Mass fraction (2) 4 1.560 1 3 -1 6.137e-01 Mole fraction - Liquid (1) 4 6.137 1 -2 6.13e-02 Mole fraction - Liquid (2) 3 6.13 1 1 3.817e+01 Ambient temperature 4 3.817 °C 2 3.1132e+02 Ambient temperature 5 3.1132 $\pu{K}$ -1 4.533e-01 Mass fraction (1) 4 4.533 1 -1 3.026e-01 Mass fraction (2) 4 3.026 1 4 -1 5.669e-01 Mole fraction - Liquid (1) 4 5.669 1 -1 1.329e-01 Mole fraction - Liquid (2) 4 1.329 1 1 3.866e+01 Ambient temperature 4 3.866 °C 2 3.1181e+02 Ambient temperature 5 3.1181 $\pu{K}$ -1 5.834e-01 Mass fraction (1) 4 5.834 1 -1 1.024e-01 Mass fraction (2) 4 1.024 1 5 -1 6.284e-01 Mole fraction - Liquid (1) 4 6.284 1 -2 3.87e-02 Mole fraction - Liquid (2) 3 3.87 1 1 3.887e+01 Ambient temperature 4 3.887 °C 2 3.1202e+02 Ambient temperature 5 3.1202 $\pu{K}$ -1 4.190e-01 Mass fraction (1) 4 4.190 1 -1 3.554e-01 Mass fraction (2) 4 3.554 1 6 -1 5.472e-01 Mole fraction - Liquid (1) 4 5.472 1 -1 1.630e-01 Mole fraction - Liquid (2) 4 1.630 1 1 3.927e+01 Ambient temperature 4 3.927 °C 2 3.1242e+02 Ambient temperature 5 3.1242 $\pu{K}$ -1 6.172e-01 Mass fraction (1) 4 6.172 1 -2 5.05e-02 Mass fraction (2) 3 5.05 1 7 -1 6.418e-01 Mole fraction - Liquid (1) 4 6.418 1 -2 1.84e-02 Mole fraction - Liquid (2) 3 1.84 1 1 4.082e+01 Ambient temperature 4 4.082 °C 2 3.1397e+02 Ambient temperature 5 3.1397 $\pu{K}$ -1 3.890e-01 Mass fraction (1) 4 3.890 1 -1 4.016e-01 Mass fraction (2) 4 4.016 1 8 -1 5.286e-01 Mole fraction - Liquid (1) 4 5.286 1 -1 1.916e-01 Mole fraction - Liquid (2) 4 1.916 1 1 4.477e+01 Ambient temperature 4 4.477 °C 2 3.1792e+02 Ambient temperature 5 3.1792 $\pu{K}$ -1 3.510e-01 Mass fraction (1) 4 3.510 1 -1 4.600e-01 Mass fraction (2) 4 4.600 1 9 -1 5.026e-01 Mole fraction - Liquid (1) 4 5.026 1 -1 2.313e-01 Mole fraction - Liquid (2) 4 2.313 1 1 Solubility, Solubility data series The synthetic method (Alekseev [1]) was used. Mixtures of (1), (2) and (3) of total mass 10 g were heated with vigorous stirring to a temperature higher than the homogenization temperature, then slowly cooled until turbidity appeared. Heating and cooling cycles were repeated twice. Temperature values obtained for appearing and disappearing turbidity were averaged. The International Union of Pure and Applied Chemistry Alekseev, V. F.; Zh. Russ. Fiz. -Khim. O-va 8, 249 (1876). paper Gudkina, L. V.; Ph.D. Dissertation, Novosibirsk Institute of Inorganic Chemistry, Russia, 1975. dissertation 75-52-5 1 CH3NO2 InChI=1S/CH3NO2/c1-2(3)4/h1H3 LYGJENNIWJXYER-UHFFFAOYSA-N 61.04 Nitromethane Source not specified; pure grade reagent; dried and twice distilled in a glass packed column. 74-95-3 2 CH2Br2 InChI=1S/CH2Br2/c2-1-3/h1H2 FJBFPHVGVWTDIP-UHFFFAOYSA-N 173.835 Dibromomethane Source not specified; pure grade reagent; dried and twice distilled in a glass packed column. 107-21-1 3 C2H6O2 InChI=1S/C2H6O2/c3-1-2-4/h3-4H,1-2H2 LYCAIKOWRPUZTN-UHFFFAOYSA-N 62.0678 1,2-Ethanediol Analytical purity; dried and twice distilled under vacuum; 0.03 mass% water by the Karl Fischer analysis. Nitromethane with Dibromomethane and 1,2-Ethanediol