{"compilation": {"title": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with 1-Pentanol and Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii P. Sazonov", "sources": [{"citation": "Zhuravleva, I. K.; Zhuravlev, E. F.; Lomakina, N. G.; Izv. Vyssh. Uchebn. Zaved.; Khim. Khim. Tekhnol. 18, 449 (1975).", "pubtype": "paper"}], "system": "Nitromethane with 1-Pentanol and Water", "substances": [{"constituent": 1, "name": "Nitromethane", "formula": "CH3NO2 ", "molweight": 61.04, "casrn": "75-52-5", "inchi": "InChI=1S/CH3NO2/c1-2(3)4/h1H3", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N", "sample": "Source not specified; purified; BP = 101.3°C; $n_{D}^{20}$ = 1.3820, $d_{4}^{20}$ = 1.1320."}, {"constituent": 2, "name": "1-Pentanol", "formula": "C5H12O", "molweight": 88.1482, "casrn": "71-41-0", "inchi": "InChI=1S/C5H12O/c1-2-3-4-5-6/h6H,2-5H2,1H3", "inchikey": "AMQJEAYHLZJPGS-UHFFFAOYSA-N", "sample": "Source not specified; purified; BP = 38°C; $n_{D}^{20}$ = 1.4100, $d_{4}^{20}$ = 0.8144."}, {"constituent": 3, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Twice distilled; $n_{D}^{20}$ = 1.3333."}], "method": "Two methods were used. The solubility temperatures of the liquid phases were determined by the synthetic method (Alekseev [1]) The analytical method described in Nikurashina and Mertslin [2] was used for determining equilibrium liquid phase compositions. Samples from coexisting liquid phases at equilibrium were analyzed by refractometry. No experimental details given.", "reference": {"citation": "Nikurashina, N. I.; Mertslin, R. V.; Method of Secants (in Russian), Saratov University, 1969.", "pubtype": "book"}, "dataset": [{"series": 2, "title": "Table 2. Compositions of three coexisting liquid phases system nitromethane + 1-pentanol + water*", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.1e+01", "significand": "1.1", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.84e+02", "significand": "2.84", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "5.54e-01", "significand": "5.54", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "3.89e-01", "significand": "3.89", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "5.45e-01", "significand": "5.45", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "2.65e-01", "significand": "2.65", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "1.1e+01", "significand": "1.1", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.84e+02", "significand": "2.84", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "4.46e-01", "significand": "4.46", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "4.73e-01", "significand": "4.73", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "4.26e-01", "significand": "4.26", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "3.13e-01", "significand": "3.13", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "1.1e+01", "significand": "1.1", "exponent": "1", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.84e+02", "significand": "2.84", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "5.1e-02", "significand": "5.1", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mass fraction (2)", "number": "2.6e-02", "significand": "2.6", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (1)", "number": "1.6e-02", "significand": "1.6", "exponent": "-2", "sigfigs": "2", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "6e-03", "significand": "6", "exponent": "-3", "sigfigs": "1", "unit": "1"}], "supplemental": []}]}, {"series": 1, "title": "Table 1. Solubility temperatures of the liquid phases", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+00", "significand": "1.5", "exponent": "0", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.747e+02", "significand": "2.747", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "8.70e-01", "significand": "8.70", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "1.05e-01", "significand": "1.05", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - Liquid (1)", "number": "8.47e-01", "significand": "8.47", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mole fraction - Liquid (2)", "number": "7.1e-02", "significand": "7.1", "exponent": "-2", "sigfigs": "2", "unit": "1"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+00", "significand": "2.0", "exponent": "0", "sigfigs": "2", "unit": "°C"}, {"property": "Ambient temperature", "number": "2.752e+02", "significand": "2.752", "exponent": "2", "sigfigs": "4", "unit": "$\\pu{K}$"}], "data": [{"property": "Mass fraction (1)", "number": "8.74e-01", "significand": "8.74", "exponent": "-1", "sigfigs": "3", "unit": "1"}, {"property": "Mass fraction (2)", "number": "1.06e-01", "significand": "1.06", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Mole fraction - 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