Nikolai V. Sazonov
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
3.23e-01
Mole fraction - Liquid (1)
3
3.23
1
-1
5.45e-01
Mole fraction - Liquid (2)
3
5.45
1
1
-1
2.81e-01
Mass fraction (1)
3
2.81
1
-1
6.85e-01
Mass fraction (2)
3
6.85
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
5.21e-01
Mole fraction - Liquid (1)
3
5.21
1
-1
3.53e-01
Mole fraction - Liquid (2)
3
3.53
1
2
-1
4.88e-01
Mass fraction (1)
3
4.88
1
-1
4.77e-01
Mass fraction (2)
3
4.77
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
6.88e-01
Mole fraction - Liquid (1)
3
6.88
1
-1
2.01e-01
Mole fraction - Liquid (2)
3
2.01
1
3
-1
6.80e-01
Mass fraction (1)
3
6.80
1
-1
2.87e-01
Mass fraction (2)
3
2.87
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-3
5e-03
Mole fraction - Liquid (1)
1
5
1
-2
1.1e-02
Mole fraction - Liquid (2)
2
1.1
1
4
-2
1.6e-02
Mass fraction (1)
2
1.6
1
-2
5.1e-02
Mass fraction (2)
2
5.1
1
1
Table 1.Mutual solubility of nitromethane, 2-methoxy-2-methylpropane and water
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
1.28e-01
Mole fraction - Liquid (1)
3
1.28
1
-1
7.76e-01
Mole fraction - Liquid (2)
3
7.76
1
1
-1
1.00e-01
Mass fraction (1)
3
1.00
1
-1
8.78e-01
Mass fraction (2)
3
8.78
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
2.25e-01
Mole fraction - Liquid (1)
3
2.25
1
-1
6.60e-01
Mole fraction - Liquid (2)
3
6.60
1
2
-1
1.86e-01
Mass fraction (1)
3
1.86
1
-1
7.86e-01
Mass fraction (2)
3
7.86
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
3.21e-01
Mole fraction - Liquid (1)
3
3.21
1
-1
5.51e-01
Mole fraction - Liquid (2)
3
5.51
1
3
-1
2.78e-01
Mass fraction (1)
3
2.78
1
-1
6.89e-01
Mass fraction (2)
3
6.89
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
5.79e-01
Mole fraction - Liquid (1)
3
5.79
1
-1
2.96e-01
Mole fraction - Liquid (2)
3
2.96
1
4
-1
5.55e-01
Mass fraction (1)
3
5.55
1
-1
4.10e-01
Mass fraction (2)
3
4.10
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-1
7.68e-01
Mole fraction - Liquid (1)
3
7.68
1
-1
1.35e-01
Mole fraction - Liquid (2)
3
1.35
1
5
-1
7.74e-01
Mass fraction (1)
3
7.74
1
-1
1.97e-01
Mass fraction (2)
3
1.97
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-2
1.0e-02
Mole fraction - Liquid (1)
2
1.0
1
-2
1.0e-02
Mole fraction - Liquid (2)
2
1.0
1
6
-2
3.2e-02
Mass fraction (1)
2
3.2
1
-2
4.6e-02
Mass fraction (2)
2
4.6
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-2
1.5e-02
Mole fraction - Liquid (1)
2
1.5
1
-3
9e-03
Mole fraction - Liquid (2)
1
9
1
7
-2
4.7e-02
Mass fraction (1)
2
4.7
1
-2
4.1e-02
Mass fraction (2)
2
4.1
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-2
1.9e-02
Mole fraction - Liquid (1)
2
1.9
1
-3
9e-03
Mole fraction - Liquid (2)
1
9
1
8
-2
6.0e-02
Mass fraction (1)
2
6.0
1
-2
4.1e-02
Mass fraction (2)
2
4.1
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-2
2.7e-02
Mole fraction - Liquid (1)
2
2.7
1
-3
6e-03
Mole fraction - Liquid (2)
1
6
1
9
-2
8.4e-02
Mass fraction (1)
2
8.4
1
-2
2.7e-02
Mass fraction (2)
2
2.7
1
1
2.0e+01
Ambient temperature
2
2.0
°C
2
2.93e+02
Ambient temperature
3
2.93
$\pu{K}$
-2
3.1e-02
Mole fraction - Liquid (1)
2
3.1
1
-3
4e-03
Mole fraction - Liquid (2)
1
4
1
10
-2
9.6e-02
Mass fraction (1)
2
9.6
1
-2
1.8e-02
Mass fraction (2)
2
1.8
1
2
Table 2. Compositions of equilibrium liquid phases ternary system
Solubility, Solubility data series
Two methods were used. The solubility curve was determined by the titration method. The compositions of equilibrium liquid phases were determined by the analytical method with the apparatus described in Kubicek et al. [1].
The International Union of Pure and Applied Chemistry
Kubicek, V.; Matous, J.; Novak, J. P.; Collect. Czech. Chem. Commun. 57, 2021 (1992).
paper
https://doi.org/10.1135/cccc19922021
Kubíček, V.; Novák, J. P.; Matouš, J.; Collect. Czech. Chem. Commun. 58, 983-95 (1993).
paper
https://doi.org/10.1135/cccc19930983
75-52-5
1
CH3NO2
InChI=1S/CH3NO2/c1-2(3)4/h1H3
LYGJENNIWJXYER-UHFFFAOYSA-N
61.04
Nitromethane
Xenon (Poland); dried with sodium and distilled on a packed column with 40 theoretical plates; $n_{D}^{20}$ = 1.3820; $\rho^{20} = \pu{1138.2 g L-1}$.
1634-04-4
2
C5H12O
InChI=1S/C5H12O/c1-5(2,3)6-4/h1-4H3
BZLVMXJERCGZMT-UHFFFAOYSA-N
88.1482
2-Methoxy-2-methylpropane
Obtained from the Synthetic Rubber Research Institute (Czech); dried with sodium and distilled on a packed column; 0.005 mass% of water by the Karl Fischer analysis; $n_{D}^{20}$ = 1.3688, $\rho^{20} = \pu{740.3 g L-1}$.
7732-18-5
3
H2O
InChI=1S/H2O/h1H2
XLYOFNOQVPJJNP-UHFFFAOYSA-N
18.0153
Water
Twice distilled.
Nitromethane with 2-Methoxy-2-methylpropane and Water
Solubility data from IUPAC SDS Volume 72 (page 1498) - Nitromethane with 2-Methoxy-2-methylpropane and Water