{"@context": ["https://stuchalk.github.io/scidata/contexts/crg_chemical.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_mixture.jsonld", "https://stuchalk.github.io/scidata/contexts/crg_substance.jsonld", "https://stuchalk.github.io/scidata/contexts/scidata.jsonld", "https://stuchalk.github.io/scidata/contexts/sol.jsonld", {"sdo": "https://stuchalk.github.io/scidata/ontology/scidata.owl#", "w3i": "https://w3id.org/skgo/modsci#", "dc": "http://purl.org/dc/terms/", "qudt": "https://qudt.org/vocab/unit/", "xsd": "http://www.w3.org/2001/XMLSchema#", "gb": "https://goldbook.iupac.org/", "so": "https://stuchalk.github.io/scidata/ontology/solubility.owl#", "ss": "http://semanticscience.org/resource/", "obo": "http://purl.obolibrary.org/obo/", "afrl": "http://purl.allotrope.org/ontologies/role#", "afq": "http://purl.allotrope.org/ontologies/quality#", "enm": "http://purl.enanomapper.org/onto/"}, {"@base": "https://srdata.unf.edu/solubility/api/compilation/4537/jsonld#"}], "@id": "", "generatedAt": "08-19-26 19:15:39", "version": "1", "@graph": {"@id": "https://srdata.unf.edu/solubility/api/compilation/4537/jsonld#", "@type": "sdo:scidataFramework", "uid": "72_59", "title": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with Heptane and Water", "authors": [{"@id": "author/1/", "@type": "dc:creator", "name": "Valerii P. Sazonov", "role": "compiler"}], "description": "Compiled solubility data reported in the IUPAC Solubility Data Series", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": ["Solubility", "Solubility data series"], "toc": ["dc:creator", "dc:rights", "dc:source", "sdo:chemical", "sdo:condition", "sdo:constituent", "sdo:datagroup", "sdo:datapoint", "sdo:dataset", "sdo:datum", "sdo:methodology", "sdo:mixture", "sdo:numericvalue", "sdo:procedure", "sdo:quantity", "sdo:scidataFramework", "sdo:scientificData", "sdo:substance", "sdo:system"], "ids": ["afrl:0000269", "obo:NCIT_C25206", "qudt:K", "sdo:numericvalue", "w3i:Chemistry", "w3i:PhysicalChemistry", "xsd:float"], "scidata": {"@id": "scidata/", "@type": "sdo:scientificData", "discipline#": "w3i:Chemistry", "subdiscipline#": "w3i:PhysicalChemistry", "methodology": {"@id": "methodology/", "@type": "sdo:methodology", "aspects": [{"@id": "procedure/1/", "@type": "sdo:procedure", "description": "The titration method was used. A glass flask with volume 100 mL and a microburette with scale division 0.01 mL were used. Five heterogeneous mixtures of two components were prepared and titrated by the third component until the third liquid phase separated. The solutions were mixed by a magnetic stirrer. The tie lines were plotted across the points obtained by titration. These five points corresponded the five initial solutions. The compositions of three coexisting liquid phases were determined by the crossing of the above mentioned tie lines.", "references": []}]}, "system": {"@id": "system/", "@type": "sdo:system", "facets": [{"@id": "substance/1/", "@type": "sdo:substance", "name": "Nitromethane", "formula": "CH3NO2 ", "casrn": "75-52-5", "iupacname": "nitromethane", "inchikey": "LYGJENNIWJXYER-UHFFFAOYSA-N"}, {"@id": "substance/2/", "@type": "sdo:substance", "name": "Heptane", "formula": "C7H16", "casrn": "142-82-5", "iupacname": "heptane", "inchikey": "IMNFDUFMRHMDMM-UHFFFAOYSA-N"}, {"@id": "substance/3/", "@type": "sdo:substance", "name": "Water", "formula": "H2O", "casrn": "7732-18-5", "iupacname": "oxidane", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}, {"@id": "chemical/1/", "@type": "sdo:chemical", "name": "Nitromethane", "description": "Source not specified, pure grade reagent; dried over $\\ce{CaCl2}$ and repeatedly distilled in a laboratory packed column of 20 theoretical plates; BP = 101.20°C; $n_{D}^{20}$ = 1.3820.", "substance#": "substance/1/"}, {"@id": "chemical/2/", "@type": "sdo:chemical", "name": "Heptane", "description": "Source not specified, CP reagent; distilled; BP = 98.42°C; $n_{D}^{20}$ = 1.3877.", "substance#": "substance/2/"}, {"@id": "chemical/3/", "@type": "sdo:chemical", "name": "Water", "description": "Twice distilled.", "substance#": "substance/3/"}, {"@id": "mixture/1/", "@type": "sdo:mixture", "name": "Nitromethane with Heptane and Water", "type": "ternary system", "constituents": [{"@id": "mixture/1/constituent/1/", "@type": "sdo:constituent", "chemical": "chemical 1", "chemical#": "chemical/1/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/2/", "@type": "sdo:constituent", "chemical": "chemical 2", "chemical#": "chemical/2/", "role": "solvent", "role#": "afrl:0000269"}, {"@id": "mixture/1/constituent/3/", "@type": "sdo:constituent", "chemical": "chemical 3", "chemical#": "chemical/3/", "role": "solvent", "role#": "afrl:0000269"}]}, {"@id": "quantity/1/", "@type": "sdo:quantity", "quantity": "Ambient temperature", "quantity#": "obo:NCIT_C25206", "unit": "Kelvin", "unit#": "qudt:K"}, {"@id": "condition/1/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "2.982e+02", "significand": 2.982, "exponent": 2, "sigfigs": 4}, {"@id": "condition/2/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.032e+02", "significand": 3.032, "exponent": 2, "sigfigs": 4}, {"@id": "condition/3/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.132e+02", "significand": 3.132, "exponent": 2, "sigfigs": 4}, {"@id": "condition/4/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.232e+02", "significand": 3.232, "exponent": 2, "sigfigs": 4}, {"@id": "condition/5/", "@type": "sdo:condition", "quantity#": "quantity/1/", "number": "3.332e+02", "significand": 3.332, "exponent": 2, "sigfigs": 4}]}, "dataset": {"@id": "dataset/", "@type": "sdo:dataset", "datagroup": [{"@id": "datagroup/1/", "@type": "sdo:datagroup", "label": "Datagroup 1", "mixture#": "mixture/1/", "datapoints": ["datapoint/1/", "datapoint/2/", "datapoint/3/", "datapoint/4/", "datapoint/5/", "datapoint/6/", "datapoint/7/", "datapoint/8/", "datapoint/9/", "datapoint/10/", "datapoint/11/", "datapoint/12/", "datapoint/13/", "datapoint/14/", "datapoint/15/"]}], "datapoint": [{"@id": "datapoint/1/", "@type": "sdo:datapoint", "uid": "72:059:001:001:001", "conditions#": ["condition/1/"], "data": [{"@id": "datapoint/1/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/1/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.70e-01", "significand": 9.7, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/1/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2e-03", "significand": 2.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/1/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/1/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.88e-01", "significand": 9.88, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/1/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/1/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3e-03", "significand": 3.0, "exponent": -3, "sigfigs": 1}}]}, {"@id": "datapoint/2/", "@type": "sdo:datapoint", "uid": "72:059:001:001:002", "conditions#": ["condition/2/"], "data": [{"@id": "datapoint/2/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/2/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.58e-01", "significand": 9.58, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/2/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5e-03", "significand": 5.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/2/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/2/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.80e-01", "significand": 9.8, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/2/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/2/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8e-03", "significand": 8.0, "exponent": -3, "sigfigs": 1}}]}, {"@id": "datapoint/3/", "@type": "sdo:datapoint", "uid": "72:059:001:001:003", "conditions#": ["condition/3/"], "data": [{"@id": "datapoint/3/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/3/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.36e-01", "significand": 9.36, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/3/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7e-03", "significand": 7.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/3/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/3/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.71e-01", "significand": 9.71, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/3/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/3/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.2e-02", "significand": 1.2, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/4/", "@type": "sdo:datapoint", "uid": "72:059:001:001:004", "conditions#": ["condition/4/"], "data": [{"@id": "datapoint/4/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/4/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.20e-01", "significand": 9.2, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/4/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.2e-02", "significand": 1.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/4/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/4/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.59e-01", "significand": 9.59, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/4/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/4/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.0e-02", "significand": 2.0, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/5/", "@type": "sdo:datapoint", "uid": "72:059:001:001:005", "conditions#": ["condition/5/"], "data": [{"@id": "datapoint/5/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/5/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.04e-01", "significand": 9.04, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/5/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.5e-02", "significand": 1.5, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/5/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/5/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.49e-01", "significand": 9.49, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/5/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/5/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.1e-02", "significand": 2.1, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/6/", "@type": "sdo:datapoint", "uid": "72:059:001:001:006", "conditions#": ["condition/6/"], "data": [{"@id": "datapoint/6/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/6/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.2e-02", "significand": 3.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/6/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/6/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.41e-01", "significand": 9.41, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/6/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/6/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.0e-02", "significand": 2.0, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/6/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/6/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.75e-01", "significand": 9.75, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/7/", "@type": "sdo:datapoint", "uid": "72:059:001:001:007", "conditions#": ["condition/7/"], "data": [{"@id": "datapoint/7/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/7/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.7e-02", "significand": 3.7, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/7/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/7/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.25e-01", "significand": 9.25, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/7/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/7/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.4e-02", "significand": 2.4, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/7/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/7/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.69e-01", "significand": 9.69, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/8/", "@type": "sdo:datapoint", "uid": "72:059:001:001:008", "conditions#": ["condition/8/"], "data": [{"@id": "datapoint/8/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/8/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.3e-02", "significand": 4.3, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/8/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/8/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.03e-01", "significand": 9.03, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/8/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/8/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.8e-02", "significand": 2.8, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/8/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/8/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.62e-01", "significand": 9.62, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/9/", "@type": "sdo:datapoint", "uid": "72:059:001:001:009", "conditions#": ["condition/9/"], "data": [{"@id": "datapoint/9/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/9/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.8e-02", "significand": 4.8, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/9/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/9/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.85e-01", "significand": 8.85, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/9/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/9/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.2e-02", "significand": 3.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/9/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/9/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.55e-01", "significand": 9.55, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/10/", "@type": "sdo:datapoint", "uid": "72:059:001:001:010", "conditions#": ["condition/10/"], "data": [{"@id": "datapoint/10/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/10/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.2e-02", "significand": 5.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/10/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/10/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "8.65e-01", "significand": 8.65, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/10/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/10/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.5e-02", "significand": 3.5, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/10/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/10/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "9.49e-01", "significand": 9.49, "exponent": -1, "sigfigs": 3}}]}, {"@id": "datapoint/11/", "@type": "sdo:datapoint", "uid": "72:059:001:001:011", "conditions#": ["condition/11/"], "data": [{"@id": "datapoint/11/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/11/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.4e-02", "significand": 3.4, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/11/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/11/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2e-03", "significand": 2.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/11/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/11/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.06e-01", "significand": 1.06, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/11/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/11/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0e-02", "significand": 1.0, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/12/", "@type": "sdo:datapoint", "uid": "72:059:001:001:012", "conditions#": ["condition/12/"], "data": [{"@id": "datapoint/12/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/12/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.8e-02", "significand": 3.8, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/12/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/12/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4e-03", "significand": 4.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/12/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/12/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.16e-01", "significand": 1.16, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/12/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/12/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "2.0e-02", "significand": 2.0, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/13/", "@type": "sdo:datapoint", "uid": "72:059:001:001:013", "conditions#": ["condition/13/"], "data": [{"@id": "datapoint/13/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/13/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.2e-02", "significand": 4.2, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/13/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/13/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "7e-03", "significand": 7.0, "exponent": -3, "sigfigs": 1}}, {"@id": "datapoint/13/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/13/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.26e-01", "significand": 1.26, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/13/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/13/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "3.4e-02", "significand": 3.4, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/14/", "@type": "sdo:datapoint", "uid": "72:059:001:001:014", "conditions#": ["condition/14/"], "data": [{"@id": "datapoint/14/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/14/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.7e-02", "significand": 4.7, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/14/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/14/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.0e-02", "significand": 1.0, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/14/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/14/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.38e-01", "significand": 1.38, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/14/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/14/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "4.8e-02", "significand": 4.8, "exponent": -2, "sigfigs": 2}}]}, {"@id": "datapoint/15/", "@type": "sdo:datapoint", "uid": "72:059:001:001:015", "conditions#": ["condition/15/"], "data": [{"@id": "datapoint/15/datum/1/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (1)", "value": {"@id": "datapoint/15/datum/1/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "5.1e-02", "significand": 5.1, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/15/datum/2/", "@type": "sdo:datum", "quantity": "Mole fraction - Liquid (2)", "value": {"@id": "datapoint/15/datum/2/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.3e-02", "significand": 1.3, "exponent": -2, "sigfigs": 2}}, {"@id": "datapoint/15/datum/3/", "@type": "sdo:datum", "quantity": "Mass fraction (1)", "value": {"@id": "datapoint/15/datum/3/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "1.46e-01", "significand": 1.46, "exponent": -1, "sigfigs": 3}}, {"@id": "datapoint/15/datum/4/", "@type": "sdo:datum", "quantity": "Mass fraction (2)", "value": {"@id": "datapoint/15/datum/4/value/1/", "@type": "sdo:numericvalue", "datatype": "xsd:float", "number": "6.1e-02", "significand": 6.1, "exponent": -2, "sigfigs": 2}}]}]}}, "sources": [{"@id": "source/1/", "@type": "dc:source", "citation": "Rezanova, E. N.; Tojkka, A. M.; Markuzin, N. P.; Vestn. Leningr. Univ.; Fiz.; Khim. 18, 53-6 (1991)."}, {"@id": "source/2/", "@type": "dc:source", "citation": "Solubility data from IUPAC SDS Volume 72 (page ?) - Nitromethane with Heptane and Water", "url": "https://doi.org/10.1063/1.1342856"}], "rights": [{"@id": "rights/1/", "@type": "dc:rights", "holder": "The International Union of Pure and Applied Chemistry (IUPAC)", "license": "https://creativecommons.org/licenses/by-nc/4.0/"}]}}