{"compilation": {"title": "Solubility data from IUPAC SDS Volume 57 (page 287) - Ethene with Cycloheptanone", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Colin L. Young", "sources": [{"citation": "Gallardo, M. A.; Lopez, M. C.; Urieta, J. S.; Gutierrez-Losa, C.; Fluid Phase Equilib. 1990, 58, 159-172.", "pubtype": "paper", "url": "https://doi.org/10.1016/0378-3812(90)87011-d"}], "system": "Ethene with Cycloheptanone", "substances": [{"constituent": 2, "name": "Cycloheptanone", "formula": "C7H12O", "molweight": 112.17, "casrn": "502-42-1", "inchi": "InChI=1S/C7H12O/c8-7-5-3-1-2-4-6-7/h1-6H2", "inchikey": "CGZZMOTZOONQIA-UHFFFAOYSA-N", "sample": "Merck and Co. sample; purity 98.2 mole%."}, {"constituent": 1, "name": "Ethene", "formula": "C2H4", "molweight": 28.0532, "casrn": "74-85-1", "inchi": "InChI=1S/C2H4/c1-2/h1-2H2", "inchikey": "VGGSQFUCUMXWEO-UHFFFAOYSA-N", "sample": "Sociedad Espa&#241;ol del Oxigeno. purity 99.90 mole%."}], "method": "The solubility apparatus, based on the design of Ben-Naim and Baer, was described earlier [1]. The essential parts were a gas buret, mercury manometer, and solution vessel. The solvent was degassed in the solution vessel. The saturation and volumetric measurements were carried out using solvent saturated gas.<br/>It appears that the mole fraction solubility at one atm was estimated from the raw data by assuming Henry's law is obeyed and that the partial pressure of the solvent is given by Raoult's law.", "reference": {"citation": "Carnicer, J.; Gibanel, F.; Urieta, J. S.; Gutierrez Losa, C.; Rev. Acad. Ciencieas. (Zaragoza) 1979, 34, 115-22.", "pubtype": "paper", "url": "https://zaguan.unizar.es/record/4447/files/S2_T34_A1979.pdf"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.7315e+02", "significand": "2.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.624e-02", "significand": "1.624", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "3.200e+01", "significand": "3.200", "exponent": "1", "sigfigs": "4", "unit": "1"}, {"property": "Bunsen Coefficient", "number": "3.200e+01", "significand": "3.200", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.8315e+02", "significand": "2.8315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.387e-02", "significand": "1.387", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.802e+01", "significand": "2.802", "exponent": "1", "sigfigs": "4", "unit": "1"}, {"property": "Bunsen Coefficient", "number": "2.703e+01", "significand": "2.703", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.9315e+02", "significand": "2.9315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.209e-02", "significand": "1.209", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.501e+01", "significand": "2.501", "exponent": "1", "sigfigs": "4", "unit": "1"}, {"property": "Bunsen Coefficient", "number": "2.331e+01", "significand": "2.331", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.9815e+02", "significand": "2.9815", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.132e-02", "significand": "1.132", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.369e+01", "significand": "2.369", "exponent": "1", "sigfigs": "4", "unit": "1"}, {"property": "Bunsen Coefficient", "number": "2.171e+01", "significand": "2.171", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.0315e+02", "significand": "3.0315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.059e-02", "significand": "1.059", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.242e+01", "significand": "2.242", "exponent": "1", "sigfigs": "4", "unit": "1"}, {"property": "Bunsen Coefficient", "number": "2.020e+01", "significand": "2.020", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": []}]}]}}