{"compilation": {"title": "Solubility data from IUPAC SDS Volume 57 (page ?) - Ethene with 1-Butanol", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Walter Hayduk", "sources": [{"citation": "Narasimhan, S.; Natarajan, G. S.; Nageshwar, G. D.; Indian J. Technol. 1981, 19, 298-299.", "pubtype": "paper"}], "system": "Ethene with 1-Butanol", "substances": [{"constituent": 1, "name": "Ethene", "formula": "C2H4", "molweight": 28.0532, "casrn": "74-85-1", "inchi": "InChI=1S/C2H4/c1-2/h1-2H2", "inchikey": "VGGSQFUCUMXWEO-UHFFFAOYSA-N", "sample": "Ethene prepared by catalytic dehydration of ethanol over activated alumina at 350-400°C and analyzed by chromatography. Purity not given."}, {"constituent": 2, "name": "1-Butanol", "formula": "C4H10O", "molweight": 74.1216, "casrn": "71-36-3", "inchi": "InChI=1S/C4H10O/c1-2-3-4-5/h5H,2-4H2,1H3", "inchikey": "LRHPLDYGYMQRHN-UHFFFAOYSA-N", "sample": "1-Butanol was treated for the removal of aldehydes and ketones and then distilled twice in a packed column."}], "method": "The solvent was held in a jacketed burette. Constant temperature water was circulated through the jacket. Gas was bubbled through the solvent until saturated. The dissolved gas content was determined by an electrometric dead-stop titration technique which yielded the bromine number. The electrometric titrator was based on a design given in [1].", "reference": {"citation": "Dubois, H. D.; Skoog, D. A.; Anal. Chem. 1948, 20, 624.", "pubtype": "paper", "url": "https://doi.org/10.1021/ac60019a008"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.9315e+02", "significand": "2.9315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "9.50e-03", "significand": "9.50", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.52e+00", "significand": "2.52", "exponent": "0", "sigfigs": "3", "unit": "1"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.9815e+02", "significand": "2.9815", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.64e-03", "significand": "8.64", "exponent": "-3", "sigfigs": "3", "unit": "1"}, {"property": "Ostwald coefficient", "number": "2.32e+00", "significand": "2.32", "exponent": "0", "sigfigs": "3", "unit": "1"}], "supplemental": []}]}]}}