{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 431) - Toluene with Seawater", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "D. Mackay, W.Y. Shiu", "sources": [{"citation": "Rossi, S. S.; Thomas, W. H.; Environ. Sci. Technol. 1981, 15, 715-6.", "pubtype": "paper", "url": "https://doi.org/10.1021/es00088a013"}], "system": "Toluene with Seawater", "substances": [{"constituent": 1, "name": "Toluene", "formula": "C7H8", "molweight": 92.1384, "casrn": "108-88-3", "inchi": "InChI=1S/C7H8/c1-7-5-3-2-4-6-7/h2-6H,1H3", "inchikey": "YXFVVABEGXRONW-UHFFFAOYSA-N"}, {"constituent": 2, "name": "Seawater", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N"}], "method": "Saturate solution was prepared by equilibrating seawater with an excess of hydrocarbon for 24 hrs. in a constant temperature gyrotary chaker followed by 12 hrs. stationary period. A 100 mL-aliquot was extracted three times with n-hexane. The concentrated hexane extract was anlzyed by a gas chromatograph equipped with a flame ionization detector to determine the hydrocarbon concentration.", "dataset": [{"series": 1, "title": "Solubility of toluene in seawater", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "1.5e+01", "significand": "1.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.2e-05", "significand": "8.2", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.1e-02", "significand": "4.1", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}, {"property": "Relative mass - solution (1)", "number": "4.1e+02", "significand": "4.1", "exponent": "2", "sigfigs": "2", "unit": "\u00b5g(1)/g(sln)"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.2e-05", "significand": "8.2", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.1e-02", "significand": "4.1", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}, {"property": "Relative mass - solution (1)", "number": "4.1e+02", "significand": "4.1", "exponent": "2", "sigfigs": "2", "unit": "\u00b5g(1)/g(sln)"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "8.4e-05", "significand": "8.4", "exponent": "-5", "sigfigs": "2", "unit": "1"}, {"property": "Relative mass - solution (1)", "number": "4.2e-02", "significand": "4.2", "exponent": "-2", "sigfigs": "2", "unit": "g<sub>1</sub>/100 g<sub>2</sub>"}, {"property": "Relative mass - solution (1)", "number": "4.185e+02", "significand": "4.185", "exponent": "2", "sigfigs": "4", "unit": "\u00b5g(1)/g(sln)"}], "supplemental": []}]}]}}