{"compilation": {"title": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Rosa Crovetto", "sources": [{"citation": "Shagiakhmetov, R. A.; Tarzimanov, A. A.; Deposited Doc. 1981, SPSTL 200 khp - D 81, 1982.", "pubtype": "report"}], "system": "Carbon dioxide with Water", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "Not stated."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not stated."}], "method": "A static method with sampling and analysis of the liquid phase was used. To attain equilibrium, the cell was gently rocked over 160 degrees.<br/>(The authors also did measurements at 298.15 K, but as the experimental pressures are greater than the $\\ce{CO2}$ vapor pressure at that temperature, the data at 298.15 K are not given here.)", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.2315e+02", "significand": "3.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "5.0e+01", "significand": "5.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.999e-02", "significand": "1.999", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "1e+01", "significand": "1", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "2.52e+01", "significand": "2.52", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.2315e+02", "significand": "3.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "5.0e+01", "significand": "5.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.293e-02", "significand": "2.293", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "2e+01", "significand": "2", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "2.90e+01", "significand": "2.90", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "2.00e+02", "significand": "2.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.2315e+02", "significand": "3.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "5.0e+01", "significand": "5.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.655e-02", "significand": "2.655", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "4e+01", "significand": "4", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "3.37e+01", "significand": "3.37", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "4.00e+02", "significand": "4.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "3.2315e+02", "significand": "3.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "5.0e+01", "significand": "5.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.854e-02", "significand": "2.854", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "6e+01", "significand": "6", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "3.63e+01", "significand": "3.63", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "6.00e+02", "significand": "6.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.7315e+02", "significand": "3.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.444e-02", "significand": "1.444", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "1e+01", "significand": "1", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "1.81e+01", "significand": "1.81", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.7315e+02", "significand": "3.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.030e-02", "significand": "2.030", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "2e+01", "significand": "2", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "2.56e+01", "significand": "2.56", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "2.00e+02", "significand": "2.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "3.7315e+02", "significand": "3.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.509e-02", "significand": "2.509", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "4e+01", "significand": "4", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "3.18e+01", "significand": "3.18", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "4.00e+02", "significand": "4.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "3.7315e+02", "significand": "3.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.907e-02", "significand": "2.907", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "6e+01", "significand": "6", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "3.70e+01", "significand": "3.70", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "6.00e+02", "significand": "6.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 9, "conditions": [{"property": "Ambient temperature", "number": "3.7315e+02", "significand": "3.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.521e-02", "significand": "3.521", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "8e+01", "significand": "8", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "4.51e+01", "significand": "4.51", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "8.00e+02", "significand": "8.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 10, "conditions": [{"property": "Ambient temperature", "number": "4.2315e+02", "significand": "4.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.50e+02", "significand": "1.50", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.160e-02", "significand": "1.160", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "1e+01", "significand": "1", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "1.45e+01", "significand": "1.45", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.00e+02", "significand": "1.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 11, "conditions": [{"property": "Ambient temperature", "number": "4.2315e+02", "significand": "4.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.50e+02", "significand": "1.50", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "2.092e-02", "significand": "2.092", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "2e+01", "significand": "2", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "2.64e+01", "significand": "2.64", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "2.00e+02", "significand": "2.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 12, "conditions": [{"property": "Ambient temperature", "number": "4.2315e+02", "significand": "4.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.50e+02", "significand": "1.50", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "3.037e-02", "significand": "3.037", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "4e+01", "significand": "4", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "3.87e+01", "significand": "3.87", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "4.00e+02", "significand": "4.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 13, "conditions": [{"property": "Ambient temperature", "number": "4.2315e+02", "significand": "4.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.50e+02", "significand": "1.50", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.291e-02", "significand": "4.291", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "6e+01", "significand": "6", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "5.54e+01", "significand": "5.54", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "6.00e+02", "significand": "6.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}, {"pntnum": 14, "conditions": [{"property": "Ambient temperature", "number": "4.2315e+02", "significand": "4.2315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "1.50e+02", "significand": "1.50", "exponent": "2", "sigfigs": "3", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.823e-02", "significand": "5.823", "exponent": "-2", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "8e+01", "significand": "8", "exponent": "1", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Solubility coefficient", "number": "7.64e+01", "significand": "7.64", "exponent": "1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "8.00e+02", "significand": "8.00", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{bar}$"}]}]}]}}