{"compilation": {"title": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Rosa Crovetto", "sources": [{"citation": "Markham, A. E.; Kobe, K. A.; J. Am. Chem. Soc. 1941, 63, 449.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01847a027"}], "system": "Carbon dioxide with Water", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "From commercial cylinder. 99.8%."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Freshly distilled and degassed."}], "method": "The apparatus was a thermostatted all-glass absorption flask provided with stirring. The solubility was calculated from the change in volume of the gas before and after equilibration at constant pressure. The partial pressure was maintained at 760 mmHg once all the corrections including solvent vapor pressure were done.", "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.7315e+02", "significand": "2.7315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2e-01", "significand": "2", "exponent": "-1", "sigfigs": "1", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "1.376e-03", "significand": "1.376", "exponent": "-3", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "7.6e+02", "significand": "7.6", "exponent": "2", "sigfigs": "2", "unit": "mm Hg"}, {"property": "Bunsen Coefficient", "number": "1.7023e+00", "significand": "1.7023", "exponent": "0", "sigfigs": "5", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.019e+00", "significand": "1.019", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.9815e+02", "significand": "2.9815", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.5e+01", "significand": "2.5", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.118e-04", "significand": "6.118", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "7.6e+02", "significand": "7.6", "exponent": "2", "sigfigs": "2", "unit": "mm Hg"}, {"property": "Bunsen Coefficient", "number": "7.565e-01", "significand": "7.565", "exponent": "-1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.045e+00", "significand": "1.045", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.1315e+02", "significand": "3.1315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "4.0e+01", "significand": "4.0", "exponent": "1", "sigfigs": "2", "unit": "°C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.152e-04", "significand": "4.152", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ambient pressure", "number": "7.6e+02", "significand": "7.6", "exponent": "2", "sigfigs": "2", "unit": "mm Hg"}, {"property": "Bunsen Coefficient", "number": "5.133e-01", "significand": "5.133", "exponent": "-1", "sigfigs": "4", "unit": "$\\pu{cm3(g) cm-3(l) atm-1}$"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.087e+00", "significand": "1.087", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}]}]}}