{"compilation": {"title": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Rosa Crovetto", "sources": [{"citation": "Wiebe, R.; Gaddy, V. L.; J. Am. Chem. Soc. 1940, 62, 815-7.", "pubtype": "paper", "url": "https://doi.org/10.1021/ja01861a033"}], "system": "Carbon dioxide with Water", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "99.98%"}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Not stated."}], "method": "<p>Apparatus and procedure are described in [1]. A high-pressure autoclave was used with stirring.</p><p>Note that some measurements were done at pressures higher than the corresponding vapor pressure of $\\ce{CO2}$. In these conditions liquid-liquid equilibria will exist.</p><p>For reference, for $\\ce{CO2}$ $T_{\\rm{c}} = \\pu{304.2 K}$ and $P_{\\rm{c}} = \\pu{72.8 atm}$.</p>", "reference": {"citation": "Wiebe, R.; Gaddy, V. L.; J. Am. Chem. 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