{"compilation": {"title": "Solubility data from IUPAC SDS Volume 62 (page ?) - Carbon dioxide with Water", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Rosa Crovetto", "sources": [{"citation": "Kunerth, W.; Phys. Rev. 1922, 2, 512-24.", "pubtype": "paper", "url": "https://doi.org/10.1103/physrev.19.512"}], "system": "Carbon dioxide with Water", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "Obtained by heating $\\ce{NaHCO3}$. Dried over $\\ce{CaCl2}$ and stored in a glass bulb."}, {"constituent": 2, "name": "Water", "formula": "H2O", "molweight": 18.0153, "casrn": "7732-18-5", "inchi": "InChI=1S/H2O/h1H2", "inchikey": "XLYOFNOQVPJJNP-UHFFFAOYSA-N", "sample": "Distilled. Tested by boiling point and density."}], "method": "McDaniel type apparatus [1].<br/>Vigorous shaking was provided to obtain equilibrium. The equilibrium composition was determined by volumetric analysis. The gas was saturated with solvent at the temperature of the measurement. Total pressure in the system was equal to the barometric pressure.", "reference": {"citation": "McDaniel, A. S.; J. Phys. Chem. 1911, 15, 587-610.", "pubtype": "paper", "url": "https://doi.org/10.1021/j150123a005"}, "dataset": [{"series": 1, "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.9315e+02", "significand": "2.9315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.0e+01", "significand": "2.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.627e-04", "significand": "6.627", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "9.00e-01", "significand": "9.00", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.9515e+02", "significand": "2.9515", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.2e+01", "significand": "2.2", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.360e-04", "significand": "6.360", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "8.72e-01", "significand": "8.72", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.9715e+02", "significand": "2.9715", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.3e+01", "significand": "2.3", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "6.038e-04", "significand": "6.038", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "8.36e-01", "significand": "8.36", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.9915e+02", "significand": "2.9915", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.6e+01", "significand": "2.6", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.720e-04", "significand": "5.720", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "8.00e-01", "significand": "8.00", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.0115e+02", "significand": "3.0115", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "2.8e+01", "significand": "2.8", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.412e-04", "significand": "5.412", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "7.65e-01", "significand": "7.65", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.0315e+02", "significand": "3.0315", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "3.0e+01", "significand": "3.0", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "5.102e-04", "significand": "5.102", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "7.29e-01", "significand": "7.29", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "3.0515e+02", "significand": "3.0515", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "3.2e+01", "significand": "3.2", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.795e-04", "significand": "4.795", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "6.93e-01", "significand": "6.93", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}, {"pntnum": 8, "conditions": [{"property": "Ambient temperature", "number": "3.0715e+02", "significand": "3.0715", "exponent": "2", "sigfigs": "5", "unit": "$\\pu{K}$"}, {"property": "Ambient temperature", "number": "3.4e+01", "significand": "3.4", "exponent": "1", "sigfigs": "2", "unit": "&deg;C"}], "data": [{"property": "Mole fraction - Liquid (1)", "number": "4.486e-04", "significand": "4.486", "exponent": "-4", "sigfigs": "4", "unit": "1"}, {"property": "Ostwald coefficient", "number": "6.56e-01", "significand": "6.56", "exponent": "-1", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Pressure (Compiler)", "number": "1.013e+00", "significand": "1.013", "exponent": "0", "sigfigs": "4", "unit": "$\\pu{bar}$"}]}]}]}}