Yuri P. Yampol'skii 1 -1.812e+01 Enthalpy change 4 -1.812 $\pu{kJ/mol}$ 1 0 -8.41e+00 Enthalpy change 3 -8.41 $\pu{kJ/mol}$ 2 1 -3.807e+01 Enthalpy change 4 -3.807 $\pu{kJ/mol}$ 3 1 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 1.78e+01 Ambient pressure 3 1.78 mm Hg -5 5.86e-05 Sorption 3 5.86 mol/cm³ 1 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 3.57e+01 Ambient pressure 3 3.57 mm Hg -5 9.75e-05 Sorption 3 9.75 mol/cm³ 2 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 5.69e+01 Ambient pressure 3 5.69 mm Hg -4 1.327e-04 Sorption 4 1.327 mol/cm³ 3 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 8.82e+01 Ambient pressure 3 8.82 mm Hg -4 1.726e-04 Sorption 4 1.726 mol/cm³ 4 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 2 1.171e+02 Ambient pressure 4 1.171 mm Hg -4 2.058e-04 Sorption 4 2.058 mol/cm³ 5 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 2 1.453e+02 Ambient pressure 4 1.453 mm Hg -4 2.322e-04 Sorption 4 2.322 mol/cm³ 6 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 2.56e+01 Ambient pressure 3 2.56 mm Hg -5 5.34e-05 Sorption 3 5.34 mol/cm³ 7 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 5.18e+01 Ambient pressure 3 5.18 mm Hg -5 8.81e-05 Sorption 3 8.81 mol/cm³ 8 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 7.81e+01 Ambient pressure 3 7.81 mm Hg -4 1.187e-04 Sorption 4 1.187 mol/cm³ 9 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 2 1.161e+02 Ambient pressure 4 1.161 mm Hg -4 1.534e-04 Sorption 4 1.534 mol/cm³ 10 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 2 1.514e+02 Ambient pressure 4 1.514 mm Hg -4 1.788e-04 Sorption 4 1.788 mol/cm³ 11 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 3.60e+01 Ambient pressure 3 3.60 mm Hg -5 4.82e-05 Sorption 3 4.82 mol/cm³ 12 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 6.70e+01 Ambient pressure 3 6.70 mm Hg -5 7.78e-05 Sorption 3 7.78 mol/cm³ 13 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 9.99e+01 Ambient pressure 3 9.99 mm Hg -4 1.047e-04 Sorption 4 1.047 mol/cm³ 14 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.151e+02 Ambient pressure 4 1.151 mm Hg -4 1.130e-04 Sorption 4 1.130 mol/cm³ 15 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.45e+02 Ambient pressure 3 1.45 mm Hg -4 1.317e-04 Sorption 4 1.317 mol/cm³ 16 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 2.93e+01 Ambient pressure 3 2.93 mm Hg -5 2.85e-05 Sorption 3 2.85 mol/cm³ 17 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 4.61e+01 Ambient pressure 3 4.61 mm Hg -5 4.20e-05 Sorption 3 4.20 mol/cm³ 18 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 8.38e+01 Ambient pressure 3 8.38 mm Hg -5 6.58e-05 Sorption 3 6.58 mol/cm³ 19 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 2 1.215e+02 Ambient pressure 4 1.215 mm Hg -5 8.81e-05 Sorption 3 8.81 mol/cm³ 20 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 2 1.403e+02 Ambient pressure 4 1.403 mm Hg -5 9.69e-05 Sorption 3 9.69 mol/cm³ 21 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 3.57e+01 Ambient pressure 3 3.57 mm Hg -5 2.33e-05 Sorption 3 2.33 mol/cm³ 22 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 5.62e+01 Ambient pressure 3 5.62 mm Hg -5 3.42e-05 Sorption 3 3.42 mol/cm³ 23 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 9.99e+01 Ambient pressure 3 9.99 mm Hg -5 5.49e-05 Sorption 3 5.49 mol/cm³ 24 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 2 1.157e+02 Ambient pressure 4 1.157 mm Hg -5 6.12e-05 Sorption 3 6.12 mol/cm³ 25 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 2 1.443e+02 Ambient pressure 4 1.443 mm Hg -5 7.36e-05 Sorption 3 7.36 mol/cm³ 26 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 1.93e+01 Ambient pressure 3 1.93 mm Hg -5 4.38e-05 Sorption 3 4.38 mol/cm³ 27 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 5.20e+01 Ambient pressure 3 5.20 mm Hg -5 8.79e-05 Sorption 3 8.79 mol/cm³ 28 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 1 7.06e+01 Ambient pressure 3 7.06 mm Hg -4 1.087e-04 Sorption 4 1.087 mol/cm³ 29 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 2 1.086e+02 Ambient pressure 4 1.086 mm Hg -4 1.370e-04 Sorption 4 1.370 mol/cm³ 30 2 3.037e+02 Ambient temperature 4 3.037 $\pu{K}$ 2 1.480e+02 Ambient pressure 4 1.480 mm Hg -4 1.635e-04 Sorption 4 1.635 mol/cm³ 31 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 2.77e+01 Ambient pressure 3 2.77 mm Hg -5 3.83e-05 Sorption 3 3.83 mol/cm³ 32 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 4.59e+01 Ambient pressure 3 4.59 mm Hg -5 5.81e-05 Sorption 3 5.81 mol/cm³ 33 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 1 6.85e+01 Ambient pressure 3 6.85 mm Hg -5 7.65e-05 Sorption 3 7.65 mol/cm³ 34 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 2 1.159e+02 Ambient pressure 4 1.159 mm Hg -4 1.082e-04 Sorption 4 1.082 mol/cm³ 35 2 3.135e+02 Ambient temperature 4 3.135 $\pu{K}$ 2 1.452e+02 Ambient pressure 4 1.452 mm Hg -4 1.242e-04 Sorption 4 1.242 mol/cm³ 36 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 3.54e+01 Ambient pressure 3 3.54 mm Hg -5 3.38e-05 Sorption 3 3.38 mol/cm³ 37 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 5.79e+01 Ambient pressure 3 5.79 mm Hg -5 4.98e-05 Sorption 3 4.98 mol/cm³ 38 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 8.39e+01 Ambient pressure 3 8.39 mm Hg -5 6.61e-05 Sorption 3 6.61 mol/cm³ 39 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.115e+02 Ambient pressure 4 1.115 mm Hg -5 8.04e-05 Sorption 3 8.04 mol/cm³ 40 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.404e+02 Ambient pressure 4 1.404 mm Hg -5 9.30e-05 Sorption 3 9.30 mol/cm³ 41 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.616e+02 Ambient pressure 4 1.616 mm Hg -4 1.001e-04 Sorption 4 1.001 mol/cm³ 42 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 2.02e+01 Ambient pressure 3 2.02 mm Hg -5 1.40e-05 Sorption 3 1.40 mol/cm³ 43 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 4.28e+01 Ambient pressure 3 4.28 mm Hg -5 2.83e-05 Sorption 3 2.83 mol/cm³ 44 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 1 7.00e+01 Ambient pressure 3 7.00 mm Hg -5 4.19e-05 Sorption 3 4.19 mol/cm³ 45 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 2 1.006e+02 Ambient pressure 4 1.006 mm Hg -5 5.61e-05 Sorption 3 5.61 mol/cm³ 46 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 2 1.316e+02 Ambient pressure 4 1.316 mm Hg -5 6.8e-05 Sorption 2 6.8 mol/cm³ 47 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ 2 1.564e+02 Ambient pressure 4 1.564 mm Hg -5 7.44e-05 Sorption 3 7.44 mol/cm³ 48 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 2.39e+01 Ambient pressure 3 2.39 mm Hg -5 1.12e-05 Sorption 3 1.12 mol/cm³ 49 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 5.11e+01 Ambient pressure 3 5.11 mm Hg -5 2.34e-05 Sorption 3 2.34 mol/cm³ 50 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 1 8.24e+01 Ambient pressure 3 8.24 mm Hg -5 3.53e-05 Sorption 3 3.53 mol/cm³ 51 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 2 1.167e+02 Ambient pressure 4 1.167 mm Hg -5 4.62e-05 Sorption 3 4.62 mol/cm³ 52 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ 2 1.493e+02 Ambient pressure 4 1.493 mm Hg -5 5.66e-05 Sorption 3 5.66 mol/cm³ 53 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 2.80e+01 Ambient pressure 3 2.80 mm Hg -5 4.00e-05 Sorption 3 4.00 mol/cm³ 54 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 4.91e+01 Ambient pressure 3 4.91 mm Hg -5 5.70e-05 Sorption 3 5.70 mol/cm³ 55 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 1 7.23e+01 Ambient pressure 3 7.23 mm Hg -5 7.61e-05 Sorption 3 7.61 mol/cm³ 56 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.123e+02 Ambient pressure 4 1.123 mm Hg -5 9.65e-05 Sorption 3 9.65 mol/cm³ 57 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.362e+02 Ambient pressure 4 1.362 mm Hg -4 1.119e-04 Sorption 4 1.119 mol/cm³ 58 2 3.233e+02 Ambient temperature 4 3.233 $\pu{K}$ 2 1.54e+02 Ambient pressure 3 1.54 mm Hg -4 1.252e-04 Sorption 4 1.252 mol/cm³ 59 2 3.386e+02 Ambient temperature 4 3.386 $\pu{K}$ 1 2.12e+01 Ambient pressure 3 2.12 mm Hg -5 1.77e-05 Sorption 3 1.77 mol/cm³ 60 2 3.386e+02 Ambient temperature 4 3.386 $\pu{K}$ 1 4.10e+01 Ambient pressure 3 4.10 mm Hg -5 3.20e-05 Sorption 3 3.20 mol/cm³ 61 2 3.386e+02 Ambient temperature 4 3.386 $\pu{K}$ 1 6.65e+01 Ambient pressure 3 6.65 mm Hg -5 4.63e-05 Sorption 3 4.63 mol/cm³ 62 2 3.386e+02 Ambient temperature 4 3.386 $\pu{K}$ 1 9.68e+01 Ambient pressure 3 9.68 mm Hg -5 5.99e-05 Sorption 3 5.99 mol/cm³ 63 2 3.386e+02 Ambient temperature 4 3.386 $\pu{K}$ 2 1.434e+02 Ambient pressure 4 1.434 mm Hg -5 7.52e-05 Sorption 3 7.52 mol/cm³ 64 2 3.48e+02 Ambient temperature 3 3.48 $\pu{K}$ 1 4.87e+01 Ambient pressure 3 4.87 mm Hg -5 2.69e-05 Sorption 3 2.69 mol/cm³ 65 2 3.48e+02 Ambient temperature 3 3.48 $\pu{K}$ 1 7.86e+01 Ambient pressure 3 7.86 mm Hg -5 3.81e-05 Sorption 3 3.81 mol/cm³ 66 2 3.48e+02 Ambient temperature 3 3.48 $\pu{K}$ 2 1.115e+02 Ambient pressure 4 1.115 mm Hg -5 5.13e-05 Sorption 3 5.13 mol/cm³ 67 2 3.48e+02 Ambient temperature 3 3.48 $\pu{K}$ 2 1.615e+02 Ambient pressure 4 1.615 mm Hg -5 6.38e-05 Sorption 3 6.38 mol/cm³ 68 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ 1 2.65e+01 Ambient pressure 3 2.65 mm Hg -5 1.33e-05 Sorption 3 1.33 mol/cm³ 69 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ 1 5.27e+01 Ambient pressure 3 5.27 mm Hg -5 2.41e-05 Sorption 3 2.41 mol/cm³ 70 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ 1 8.49e+01 Ambient pressure 3 8.49 mm Hg -5 3.39e-05 Sorption 3 3.39 mol/cm³ 71 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ 2 1.195e+02 Ambient pressure 4 1.195 mm Hg -5 4.61e-05 Sorption 3 4.61 mol/cm³ 72 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ 2 1.567e+02 Ambient pressure 4 1.567 mm Hg -5 5.52e-05 Sorption 3 5.52 mol/cm³ 73 2 2 3.03e+02 Ambient temperature 3 3.03 $\pu{K}$ -1 1.656e-01 Henry's Law Solubility Coefficient 4 1.656 $\pu{cm3(g) cm-3(s) atm-1}$ 0 3.71e+00 Langmuir sorption capacity parameter 3 3.71 $\pu{cm3/cm3}$ -1 2.173e-01 Affinity Coefficient 4 2.173 $\pu{atm-1}$ 1 2 3.13e+02 Ambient temperature 3 3.13 $\pu{K}$ -1 1.161e-01 Henry's Law Solubility Coefficient 4 1.161 $\pu{cm3(g) cm-3(s) atm-1}$ 0 3.73e+00 Langmuir sorption capacity parameter 3 3.73 $\pu{cm3/cm3}$ -1 1.232e-01 Affinity Coefficient 4 1.232 $\pu{atm-1}$ 2 2 3.23e+02 Ambient temperature 3 3.23 $\pu{K}$ -1 1.020e-01 Henry's Law Solubility Coefficient 4 1.020 $\pu{cm3(g) cm-3(s) atm-1}$ 0 2.30e+00 Langmuir sorption capacity parameter 3 2.30 $\pu{cm3/cm3}$ -1 1.297e-01 Affinity Coefficient 4 1.297 $\pu{atm-1}$ 3 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ -1 1.007e-01 Henry's Law Solubility Coefficient 4 1.007 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.28e+00 Langmuir sorption capacity parameter 3 1.28 $\pu{cm3/cm3}$ -1 1.395e-01 Affinity Coefficient 4 1.395 $\pu{atm-1}$ 4 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ -2 6.10e-02 Henry's Law Solubility Coefficient 3 6.10 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.30e+00 Langmuir sorption capacity parameter 3 1.30 $\pu{cm3/cm3}$ -1 1.005e-01 Affinity Coefficient 4 1.005 $\pu{atm-1}$ 5 2 3.03e+02 Ambient temperature 3 3.03 $\pu{K}$ -2 9.09e-02 Henry's Law Solubility Coefficient 3 9.09 $\pu{cm3(g) cm-3(s) atm-1}$ 0 3.34e+00 Langmuir sorption capacity parameter 3 3.34 $\pu{cm3/cm3}$ -1 1.810e-01 Affinity Coefficient 4 1.810 $\pu{atm-1}$ 6 2 3.13e+02 Ambient temperature 3 3.13 $\pu{K}$ -2 6.14e-02 Henry's Law Solubility Coefficient 3 6.14 $\pu{cm3(g) cm-3(s) atm-1}$ 0 2.94e+00 Langmuir sorption capacity parameter 3 2.94 $\pu{cm3/cm3}$ -3 8.7e-03 Affinity Coefficient 2 8.7 $\pu{atm-1}$ 7 2 3.23e+02 Ambient temperature 3 3.23 $\pu{K}$ -2 9.78e-02 Henry's Law Solubility Coefficient 3 9.78 $\pu{cm3(g) cm-3(s) atm-1}$ -1 7.5e-01 Langmuir sorption capacity parameter 2 7.5 $\pu{cm3/cm3}$ -1 4.587e-01 Affinity Coefficient 4 4.587 $\pu{atm-1}$ 8 2 3.33e+02 Ambient temperature 3 3.33 $\pu{K}$ -2 5.52e-02 Henry's Law Solubility Coefficient 3 5.52 $\pu{cm3(g) cm-3(s) atm-1}$ 0 2.03e+00 Langmuir sorption capacity parameter 3 2.03 $\pu{cm3/cm3}$ -2 6.88e-02 Affinity Coefficient 3 6.88 $\pu{atm-1}$ 9 2 3.43e+02 Ambient temperature 3 3.43 $\pu{K}$ -2 6.98e-02 Henry's Law Solubility Coefficient 3 6.98 $\pu{cm3(g) cm-3(s) atm-1}$ -1 5.1e-01 Langmuir sorption capacity parameter 2 5.1 $\pu{cm3/cm3}$ -1 1.362e-01 Affinity Coefficient 4 1.362 $\pu{atm-1}$ 10 2 3.23e+02 Ambient temperature 3 3.23 $\pu{K}$ -1 1.023e-01 Henry's Law Solubility Coefficient 4 1.023 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.68e+00 Langmuir sorption capacity parameter 3 1.68 $\pu{cm3/cm3}$ -1 2.074e-01 Affinity Coefficient 4 2.074 $\pu{atm-1}$ 11 2 3.38e+02 Ambient temperature 3 3.38 $\pu{K}$ -2 6.99e-02 Henry's Law Solubility Coefficient 3 6.99 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.45e+00 Langmuir sorption capacity parameter 3 1.45 $\pu{cm3/cm3}$ -1 1.149e-01 Affinity Coefficient 4 1.149 $\pu{atm-1}$ 12 2 3.48e+02 Ambient temperature 3 3.48 $\pu{K}$ -2 3.90e-02 Henry's Law Solubility Coefficient 3 3.90 $\pu{cm3(g) cm-3(s) atm-1}$ 0 2.37e+00 Langmuir sorption capacity parameter 3 2.37 $\pu{cm3/cm3}$ -2 6.38e-02 Affinity Coefficient 3 6.38 $\pu{atm-1}$ 13 2 3.53e+02 Ambient temperature 3 3.53 $\pu{K}$ -2 3.46e-02 Henry's Law Solubility Coefficient 3 3.46 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.26e+00 Langmuir sorption capacity parameter 3 1.26 $\pu{cm3/cm3}$ -2 8.94e-02 Affinity Coefficient 3 8.94 $\pu{atm-1}$ 14 3 Solubility, Solubility data series A glass volumetric apparatus was employed. The sorption system was immersed in a thermostat and the pressure was read by a cathetometer. A nonlinear least squares program was used to calculate sorption parameters as in [1]. The International Union of Pure and Applied Chemistry Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687. paper https://doi.org/10.1002/pol.1976.180140410 Barrer, R. M.; Barrie, J. A.; Slater, J.; J. Polym. Sci. 1958, 27(115), 177-197. paper https://doi.org/10.1002/pol.1958.1202711515 Chan, A. H.; Koros, W. J.; Paul, D. R.; J. Membr. Sci. 3, 117 (1978). paper https://doi.org/10.1016/s0376-7388(00)83017-3 9004-57-3 2 C23H24N6O4 InChI=1S/C23H24N6O4/c1-4-5-8-28(9-10-33-17(3)30)20-6-7-22(16(2)11-20)26-27-23-18(14-24)12-21(29(31)32)13-19(23)15-25/h6-7,11-13H,4-5,8-10H2,1-3H3 ARSKJXYLLONUAJ-UHFFFAOYSA-N 440.5 Ethyl Cellulose EC: Standard Ethocel, $\rho = \pu{1.13 g mL-1}$, M = 35 000. 106-97-8 1 C4H10 InChI=1S/C4H10/c1-3-4-2/h3-4H2,1-2H3 IJDNQMDRQITEOD-UHFFFAOYSA-N 58.1222 Butane 75-28-5 1 C4H10 InChI=1S/C4H10/c1-4(2)3/h4H,1-3H3 NNPPMTNAJDCUHE-UHFFFAOYSA-N 58.1222 2-Methylpropane 463-82-1 1 C5H12 InChI=1S/C5H12/c1-5(2,3)4/h1-4H3 CRSOQBOWXPBRES-UHFFFAOYSA-N 72.1488 2,2-Dimethylpropane n-Butane, 2-Methylpropane, 2,2-Dimethylpropane and Ethyl Cellulose (EC)