{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide, Methane and Polyarylate Ardel (PA)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Yuri P. Yampol'skii", "sources": [{"citation": "Sheu, F. R.; Chern, R. T.; Stannett, V. T.; Hopfenberg, H. B.; J. Polym. Sci. B: Polym. Phys. 26, 883-892 (1988).", "pubtype": "paper", "url": "https://doi.org/10.1002/polb.1988.090260413"}], "system": "Carbon dioxide, Methane and Polyarylate Ardel (PA)", "substances": [{"constituent": 2, "name": "Polyarylate (PA)", "formula": "C31H24Cl4O6", "molweight": 634.3, "casrn": "25639-68-3", "inchi": "InChI=1S/C15H16O2.2C8H4Cl2O2/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;9-7(11)5-1-2-6(4-3-5)8(10)12;9-7(11)5-2-1-3-6(4-5)8(10)12/h3-10,16-17H,1-2H3;2*1-4H", "inchikey": "OMASQHQNYSCEEZ-UHFFFAOYSA-N", "sample": "PA: Union Carbide Co., $\\rho = \\pu{1.204 g mL-1}$, $T_{\\rm{g}}$ = 463 K."}, {"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Methane", "formula": "CH4", "molweight": 16.0425, "casrn": "74-82-8", "inchi": "InChI=1S/CH4/h1H4", "inchikey": "VNWKTOKETHGBQD-UHFFFAOYSA-N"}], "method": "Sorption apparatus and procedure were the same as in [1].", "reference": {"citation": "Sanders, E. S.; Koros, W. J.; Hopfenberg, H. B.; Stannett, V. T.; J. Membr. Sci. 1983, 13, 161.", "pubtype": "paper", "url": "https://doi.org/10.1016/s0376-7388(00)80159-3"}, "dataset": [{"series": 1, "title": "Table 1. Dual mode sorption parameters for gases in polyarylate at 308 K", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "9.8e-01", "significand": "9.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.98e+01", "significand": "1.98", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "3.0e-01", "significand": "3.0", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "2.7e-01", "significand": "2.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "9.0e+00", "significand": "9.0", "exponent": "0", "sigfigs": "2", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.2e-01", "significand": "1.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}, {"series": 2, "title": "Table 2. Sorption isotherms of carbon dioxide and methane in polyarylate at 308 K (The original data were represented graphically)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9e-02", "significand": "9", "exponent": "-2", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "4.55e+00", "significand": "4.55", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.2e-01", "significand": "1.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "5.87e+00", "significand": "5.87", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.3e-01", "significand": "1.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "6.75e+00", "significand": "6.75", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.7e-01", "significand": "1.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "7.91e+00", "significand": "7.91", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.9e-01", "significand": "2.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.110e+01", "significand": "1.110", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.2e-01", "significand": "3.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.226e+01", "significand": "1.226", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.9e-01", "significand": "3.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.370e+01", "significand": "1.370", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Ambient pressure", "number": "4.8e-01", "significand": "4.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.587e+01", "significand": "1.587", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.8e-01", "significand": "5.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.744e+01", "significand": "1.744", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.3e-01", "significand": "6.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.845e+01", "significand": "1.845", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.8e-01", "significand": "6.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.931e+01", "significand": "1.931", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 12, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.8e-01", "significand": "7.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.118e+01", "significand": "2.118", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 13, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9.7e-01", "significand": "9.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.388e+01", "significand": "2.388", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 14, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.08e+00", "significand": "1.08", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.544e+01", "significand": "2.544", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 15, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.14e+00", "significand": "1.14", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.630e+01", "significand": "2.630", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 16, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.21e+00", "significand": "1.21", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.685e+01", "significand": "2.685", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 17, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.44e+00", "significand": "1.44", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.983e+01", "significand": "2.983", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 18, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.63e+00", "significand": "1.63", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.179e+01", "significand": "3.179", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 19, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.73e+00", "significand": "1.73", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.292e+01", "significand": "3.292", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 20, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.77e+00", "significand": "1.77", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.364e+01", "significand": "3.364", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 21, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.92e+00", "significand": "1.92", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.504e+01", "significand": "3.504", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 22, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.19e+00", "significand": "2.19", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.785e+01", "significand": "3.785", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 23, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.2e-01", "significand": "1.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.41e+00", "significand": "1.41", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 24, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.3e-01", "significand": "3.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.15e+00", "significand": "3.15", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 25, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.3e-01", "significand": "5.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "4.62e+00", "significand": "4.62", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 26, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.2e-01", "significand": "7.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "5.79e+00", "significand": "5.79", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 27, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9.6e-01", "significand": "9.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "7.21e+00", "significand": "7.21", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 28, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.11e+00", "significand": "1.11", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "8.03e+00", "significand": "8.03", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 29, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.31e+00", "significand": "1.31", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "9.06e+00", "significand": "9.06", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 30, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.59e+00", "significand": "1.59", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.021e+01", "significand": "1.021", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 31, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.85e+00", "significand": "1.85", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.119e+01", "significand": "1.119", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 32, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.21e+00", "significand": "2.21", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.242e+01", "significand": "1.242", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}]}]}}