Alexandre K. Bokarev 2 3.08e+02 Ambient temperature 3 3.08 $\pu{K}$ -1 6.31e-01 Henry's Law Solubility Coefficient 3 6.31 $\pu{cm3(g) cm-3(s) atm-1}$ 1 2.269e+01 Langmuir sorption capacity parameter 4 2.269 $\pu{cm3/cm3}$ -1 2.15e-01 Affinity Coefficient 3 2.15 $\pu{atm-1}$ 1 2 3.08e+02 Ambient temperature 3 3.08 $\pu{K}$ 0 6.45e+00 Langmuir sorption capacity parameter 3 6.45 $\pu{cm3/cm3}$ -1 1.00e-01 Affinity Coefficient 3 1.00 $\pu{atm-1}$ 2 2 3.08e+02 Ambient temperature 3 3.08 $\pu{K}$ -2 8.1e-02 Henry's Law Solubility Coefficient 2 8.1 $\pu{cm3(g) cm-3(s) atm-1}$ 0 1.32e+00 Langmuir sorption capacity parameter 3 1.32 $\pu{cm3/cm3}$ -2 7.4e-02 Affinity Coefficient 2 7.4 $\pu{atm-1}$ 3 1 -1 2.1e-01 Ambient pressure 2 2.1 $\pu{MPa}$ 0 7.30e+00 Sorption 3 7.30 $\pu{V_{1}/V_{2}}$ 1 -1 2.7e-01 Ambient pressure 2 2.7 $\pu{MPa}$ 0 9.17e+00 Sorption 3 9.17 $\pu{V_{1}/V_{2}}$ 2 -1 3.1e-01 Ambient pressure 2 3.1 $\pu{MPa}$ 1 1.011e+01 Sorption 4 1.011 $\pu{V_{1}/V_{2}}$ 3 -1 3.5e-01 Ambient pressure 2 3.5 $\pu{MPa}$ 1 1.114e+01 Sorption 4 1.114 $\pu{V_{1}/V_{2}}$ 4 -1 6.0e-01 Ambient pressure 2 6.0 $\pu{MPa}$ 1 1.581e+01 Sorption 4 1.581 $\pu{V_{1}/V_{2}}$ 5 -1 6.5e-01 Ambient pressure 2 6.5 $\pu{MPa}$ 1 1.674e+01 Sorption 4 1.674 $\pu{V_{1}/V_{2}}$ 6 -1 7.3e-01 Ambient pressure 2 7.3 $\pu{MPa}$ 1 1.833e+01 Sorption 4 1.833 $\pu{V_{1}/V_{2}}$ 7 -1 9.7e-01 Ambient pressure 2 9.7 $\pu{MPa}$ 1 2.103e+01 Sorption 4 2.103 $\pu{V_{1}/V_{2}}$ 8 0 1.04e+00 Ambient pressure 3 1.04 $\pu{MPa}$ 1 2.196e+01 Sorption 4 2.196 $\pu{V_{1}/V_{2}}$ 9 0 1.13e+00 Ambient pressure 3 1.13 $\pu{MPa}$ 1 2.327e+01 Sorption 4 2.327 $\pu{V_{1}/V_{2}}$ 10 0 1.38e+00 Ambient pressure 3 1.38 $\pu{MPa}$ 1 2.549e+01 Sorption 4 2.549 $\pu{V_{1}/V_{2}}$ 11 0 1.46e+00 Ambient pressure 3 1.46 $\pu{MPa}$ 1 2.652e+01 Sorption 4 2.652 $\pu{V_{1}/V_{2}}$ 12 0 1.58e+00 Ambient pressure 3 1.58 $\pu{MPa}$ 1 2.772e+01 Sorption 4 2.772 $\pu{V_{1}/V_{2}}$ 13 0 1.84e+00 Ambient pressure 3 1.84 $\pu{MPa}$ 1 2.938e+01 Sorption 4 2.938 $\pu{V_{1}/V_{2}}$ 14 0 1.91e+00 Ambient pressure 3 1.91 $\pu{MPa}$ 1 2.994e+01 Sorption 4 2.994 $\pu{V_{1}/V_{2}}$ 15 0 2.30e+00 Ambient pressure 3 2.30 $\pu{MPa}$ 1 3.308e+01 Sorption 4 3.308 $\pu{V_{1}/V_{2}}$ 16 0 2.33e+00 Ambient pressure 3 2.33 $\pu{MPa}$ 1 3.336e+01 Sorption 4 3.336 $\pu{V_{1}/V_{2}}$ 17 -1 2.6e-01 Ambient pressure 2 2.6 $\pu{MPa}$ 0 1.65e+00 Sorption 3 1.65 $\pu{V_{1}/V_{2}}$ 18 -1 3.2e-01 Ambient pressure 2 3.2 $\pu{MPa}$ 0 1.98e+00 Sorption 3 1.98 $\pu{V_{1}/V_{2}}$ 19 -1 3.6e-01 Ambient pressure 2 3.6 $\pu{MPa}$ 0 2.22e+00 Sorption 3 2.22 $\pu{V_{1}/V_{2}}$ 20 -1 4.2e-01 Ambient pressure 2 4.2 $\pu{MPa}$ 0 2.53e+00 Sorption 3 2.53 $\pu{V_{1}/V_{2}}$ 21 -1 6.2e-01 Ambient pressure 2 6.2 $\pu{MPa}$ 0 3.39e+00 Sorption 3 3.39 $\pu{V_{1}/V_{2}}$ 22 -1 7.0e-01 Ambient pressure 2 7.0 $\pu{MPa}$ 0 3.82e+00 Sorption 3 3.82 $\pu{V_{1}/V_{2}}$ 23 -1 7.8e-01 Ambient pressure 2 7.8 $\pu{MPa}$ 0 4.09e+00 Sorption 3 4.09 $\pu{V_{1}/V_{2}}$ 24 -1 8.5e-01 Ambient pressure 2 8.5 $\pu{MPa}$ 0 4.44e+00 Sorption 3 4.44 $\pu{V_{1}/V_{2}}$ 25 0 1.04e+00 Ambient pressure 3 1.04 $\pu{MPa}$ 0 4.97e+00 Sorption 3 4.97 $\pu{V_{1}/V_{2}}$ 26 0 1.13e+00 Ambient pressure 3 1.13 $\pu{MPa}$ 0 5.40e+00 Sorption 3 5.40 $\pu{V_{1}/V_{2}}$ 27 0 1.21e+00 Ambient pressure 3 1.21 $\pu{MPa}$ 0 5.66e+00 Sorption 3 5.66 $\pu{V_{1}/V_{2}}$ 28 0 1.29e+00 Ambient pressure 3 1.29 $\pu{MPa}$ 0 5.95e+00 Sorption 3 5.95 $\pu{V_{1}/V_{2}}$ 29 0 1.48e+00 Ambient pressure 3 1.48 $\pu{MPa}$ 0 6.38e+00 Sorption 3 6.38 $\pu{V_{1}/V_{2}}$ 30 0 1.56e+00 Ambient pressure 3 1.56 $\pu{MPa}$ 0 6.71e+00 Sorption 3 6.71 $\pu{V_{1}/V_{2}}$ 31 0 1.65e+00 Ambient pressure 3 1.65 $\pu{MPa}$ 0 6.97e+00 Sorption 3 6.97 $\pu{V_{1}/V_{2}}$ 32 0 1.74e+00 Ambient pressure 3 1.74 $\pu{MPa}$ 0 7.23e+00 Sorption 3 7.23 $\pu{V_{1}/V_{2}}$ 33 0 1.92e+00 Ambient pressure 3 1.92 $\pu{MPa}$ 0 7.66e+00 Sorption 3 7.66 $\pu{V_{1}/V_{2}}$ 34 0 2.02e+00 Ambient pressure 3 2.02 $\pu{MPa}$ 0 7.92e+00 Sorption 3 7.92 $\pu{V_{1}/V_{2}}$ 35 0 2.12e+00 Ambient pressure 3 2.12 $\pu{MPa}$ 0 8.16e+00 Sorption 3 8.16 $\pu{V_{1}/V_{2}}$ 36 0 2.18e+00 Ambient pressure 3 2.18 $\pu{MPa}$ 0 8.31e+00 Sorption 3 8.31 $\pu{V_{1}/V_{2}}$ 37 -1 1.9e-01 Ambient pressure 2 1.9 $\pu{MPa}$ -1 3.0e-01 Sorption 2 3.0 $\pu{V_{1}/V_{2}}$ 38 -1 2.3e-01 Ambient pressure 2 2.3 $\pu{MPa}$ -1 3.7e-01 Sorption 2 3.7 $\pu{V_{1}/V_{2}}$ 39 -1 3.0e-01 Ambient pressure 2 3.0 $\pu{MPa}$ -1 4.4e-01 Sorption 2 4.4 $\pu{V_{1}/V_{2}}$ 40 -1 3.3e-01 Ambient pressure 2 3.3 $\pu{MPa}$ -1 5.4e-01 Sorption 2 5.4 $\pu{V_{1}/V_{2}}$ 41 -1 4.0e-01 Ambient pressure 2 4.0 $\pu{MPa}$ -1 5.4e-01 Sorption 2 5.4 $\pu{V_{1}/V_{2}}$ 42 -1 4.4e-01 Ambient pressure 2 4.4 $\pu{MPa}$ -1 6.3e-01 Sorption 2 6.3 $\pu{V_{1}/V_{2}}$ 43 -1 5.9e-01 Ambient pressure 2 5.9 $\pu{MPa}$ -1 7.8e-01 Sorption 2 7.8 $\pu{V_{1}/V_{2}}$ 44 -1 6.8e-01 Ambient pressure 2 6.8 $\pu{MPa}$ -1 8.9e-01 Sorption 2 8.9 $\pu{V_{1}/V_{2}}$ 45 -1 7.0e-01 Ambient pressure 2 7.0 $\pu{MPa}$ -1 9.8e-01 Sorption 2 9.8 $\pu{V_{1}/V_{2}}$ 46 -1 8.5e-01 Ambient pressure 2 8.5 $\pu{MPa}$ 0 1.13e+00 Sorption 3 1.13 $\pu{V_{1}/V_{2}}$ 47 -1 9.2e-01 Ambient pressure 2 9.2 $\pu{MPa}$ 0 1.20e+00 Sorption 3 1.20 $\pu{V_{1}/V_{2}}$ 48 0 1.03e+00 Ambient pressure 3 1.03 $\pu{MPa}$ 0 1.30e+00 Sorption 3 1.30 $\pu{V_{1}/V_{2}}$ 49 0 1.11e+00 Ambient pressure 3 1.11 $\pu{MPa}$ 0 1.39e+00 Sorption 3 1.39 $\pu{V_{1}/V_{2}}$ 50 0 1.19e+00 Ambient pressure 3 1.19 $\pu{MPa}$ 0 1.52e+00 Sorption 3 1.52 $\pu{V_{1}/V_{2}}$ 51 0 1.29e+00 Ambient pressure 3 1.29 $\pu{MPa}$ 0 1.61e+00 Sorption 3 1.61 $\pu{V_{1}/V_{2}}$ 52 0 1.40e+00 Ambient pressure 3 1.40 $\pu{MPa}$ 0 1.70e+00 Sorption 3 1.70 $\pu{V_{1}/V_{2}}$ 53 0 1.49e+00 Ambient pressure 3 1.49 $\pu{MPa}$ 0 1.74e+00 Sorption 3 1.74 $\pu{V_{1}/V_{2}}$ 54 0 1.57e+00 Ambient pressure 3 1.57 $\pu{MPa}$ 0 1.87e+00 Sorption 3 1.87 $\pu{V_{1}/V_{2}}$ 55 0 1.64e+00 Ambient pressure 3 1.64 $\pu{MPa}$ 0 2.04e+00 Ambient pressure 3 2.04 $\pu{MPa}$ 0 1.98e+00 Sorption 3 1.98 $\pu{V_{1}/V_{2}}$ 0 2.26e+00 Sorption 3 2.26 $\pu{V_{1}/V_{2}}$ 56 0 1.75e+00 Ambient pressure 3 1.75 $\pu{MPa}$ 0 2.22e+00 Ambient pressure 3 2.22 $\pu{MPa}$ 0 2.04e+00 Sorption 3 2.04 $\pu{V_{1}/V_{2}}$ 0 2.46e+00 Sorption 3 2.46 $\pu{V_{1}/V_{2}}$ 57 0 1.82e+00 Ambient pressure 3 1.82 $\pu{MPa}$ 0 2.15e+00 Sorption 3 2.15 $\pu{V_{1}/V_{2}}$ 58 0 1.94e+00 Ambient pressure 3 1.94 $\pu{MPa}$ 0 2.19e+00 Sorption 3 2.19 $\pu{V_{1}/V_{2}}$ 59 2 Solubility, Solubility data series The sorption apparatus and procedures used in the present sorption experiments are the same as described earlier [1]. The International Union of Pure and Applied Chemistry Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687. paper https://doi.org/10.1002/pol.1976.180140410 Barbari, T. A.; Koros, W. J.; Paul, D. R.; J. Polym. Sci. B: Polym. Phys. 26, 729-744 (1988). paper https://doi.org/10.1002/polb.1988.090260402 25639-68-3 2 C31H24Cl4O6 InChI=1S/C15H16O2.2C8H4Cl2O2/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;9-7(11)5-1-2-6(4-3-5)8(10)12;9-7(11)5-2-1-3-6(4-5)8(10)12/h3-10,16-17H,1-2H3;2*1-4H OMASQHQNYSCEEZ-UHFFFAOYSA-N 634.3 Polyarylate (PA) 7727-37-9 1 N2 InChI=1S/N2/c1-2 IJGRMHOSHXDMSA-UHFFFAOYSA-N 28.0134 Nitrogen (Molecule) $\ce{CO2}$, $\ce{CH4}$, $\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\rho = \pu{1.21 g mL-1}$, $T_{\rm{g}}$ = 457 K. 124-38-9 1 CO2 InChI=1S/CO2/c2-1-3 CURLTUGMZLYLDI-UHFFFAOYSA-N 44.0095 Carbon dioxide $\ce{CO2}$, $\ce{CH4}$, $\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\rho = \pu{1.21 g mL-1}$, $T_{\rm{g}}$ = 457 K. 74-82-8 1 CH4 InChI=1S/CH4/h1H4 VNWKTOKETHGBQD-UHFFFAOYSA-N 16.0425 Methane $\ce{CO2}$, $\ce{CH4}$, $\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\rho = \pu{1.21 g mL-1}$, $T_{\rm{g}}$ = 457 K. Nitrogen, Carbon dioxide, Methane and Polyarylate Ardel (PA)