{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Nitrogen, Carbon dioxide, Methane and Polyarylate Ardel (PA)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Alexandre K. Bokarev", "sources": [{"citation": "Barbari, T. A.; Koros, W. J.; Paul, D. R.; J. Polym. Sci. B: Polym. Phys. 26, 729-744 (1988).", "pubtype": "paper", "url": "https://doi.org/10.1002/polb.1988.090260402"}], "system": "Nitrogen, Carbon dioxide, Methane and Polyarylate Ardel (PA)", "substances": [{"constituent": 2, "name": "Polyarylate (PA)", "formula": "C31H24Cl4O6", "molweight": 634.3, "casrn": "25639-68-3", "inchi": "InChI=1S/C15H16O2.2C8H4Cl2O2/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;9-7(11)5-1-2-6(4-3-5)8(10)12;9-7(11)5-2-1-3-6(4-5)8(10)12/h3-10,16-17H,1-2H3;2*1-4H", "inchikey": "OMASQHQNYSCEEZ-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Nitrogen (Molecule)", "formula": "N2", "molweight": 28.0134, "casrn": "7727-37-9", "inchi": "InChI=1S/N2/c1-2", "inchikey": "IJGRMHOSHXDMSA-UHFFFAOYSA-N", "sample": "$\\ce{CO2}$, $\\ce{CH4}$, $\\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\\rho = \\pu{1.21 g mL-1}$, $T_{\\rm{g}}$ = 457 K."}, {"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "$\\ce{CO2}$, $\\ce{CH4}$, $\\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\\rho = \\pu{1.21 g mL-1}$, $T_{\\rm{g}}$ = 457 K."}, {"constituent": 1, "name": "Methane", "formula": "CH4", "molweight": 16.0425, "casrn": "74-82-8", "inchi": "InChI=1S/CH4/h1H4", "inchikey": "VNWKTOKETHGBQD-UHFFFAOYSA-N", "sample": "$\\ce{CO2}$, $\\ce{CH4}$, $\\ce{N2}$: purity > 99.99%. PA (Ardel D-100): Union Carbide Co., $\\rho = \\pu{1.21 g mL-1}$, $T_{\\rm{g}}$ = 457 K."}], "method": "The sorption apparatus and procedures used in the present sorption experiments are the same as described earlier [1].", "reference": {"citation": "Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.", "pubtype": "paper", "url": "https://doi.org/10.1002/pol.1976.180140410"}, "dataset": [{"series": 1, "title": "Table 1. Dual mode sorption parameters for gases in polyarylate at 308 K", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.31e-01", "significand": "6.31", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "2.269e+01", "significand": "2.269", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.15e-01", "significand": "2.15", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Langmuir sorption capacity parameter", "number": "6.45e+00", "significand": "6.45", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.00e-01", "significand": "1.00", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "8.1e-02", "significand": "8.1", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.32e+00", "significand": "1.32", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "7.4e-02", "significand": "7.4", "exponent": "-2", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}, {"series": 2, "title": "Table 2. Sorption isotherms of various gases in polyarylate at 308 K (The original data were represented graphically)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.1e-01", "significand": "2.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "7.30e+00", "significand": "7.30", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.7e-01", "significand": "2.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "9.17e+00", "significand": "9.17", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.1e-01", "significand": "3.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.011e+01", "significand": "1.011", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.5e-01", "significand": "3.5", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.114e+01", "significand": "1.114", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.0e-01", "significand": "6.0", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.581e+01", "significand": "1.581", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.5e-01", "significand": "6.5", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.674e+01", "significand": "1.674", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.3e-01", "significand": "7.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.833e+01", "significand": "1.833", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9.7e-01", "significand": "9.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.103e+01", "significand": "2.103", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.04e+00", "significand": "1.04", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.196e+01", "significand": "2.196", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.13e+00", "significand": "1.13", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.327e+01", "significand": "2.327", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.38e+00", "significand": "1.38", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.549e+01", "significand": "2.549", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 12, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.46e+00", "significand": "1.46", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.652e+01", "significand": "2.652", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 13, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.58e+00", "significand": "1.58", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.772e+01", "significand": "2.772", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 14, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.84e+00", "significand": "1.84", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.938e+01", "significand": "2.938", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 15, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.91e+00", "significand": "1.91", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.994e+01", "significand": "2.994", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 16, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.30e+00", "significand": "2.30", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.308e+01", "significand": "3.308", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 17, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.33e+00", "significand": "2.33", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.336e+01", "significand": "3.336", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 18, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.6e-01", "significand": "2.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.65e+00", "significand": "1.65", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 19, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.2e-01", "significand": "3.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.98e+00", "significand": "1.98", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 20, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.6e-01", "significand": "3.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.22e+00", "significand": "2.22", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 21, "conditions": [], "data": [{"property": "Ambient pressure", "number": "4.2e-01", "significand": "4.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.53e+00", "significand": "2.53", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 22, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.2e-01", "significand": "6.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.39e+00", "significand": "3.39", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 23, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.0e-01", "significand": "7.0", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.82e+00", "significand": "3.82", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 24, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.8e-01", "significand": "7.8", "exponent": "-1", "sigfigs": "2", 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