Valerii I. Bondar
0
1.09e+00
Henry's Law Solubility Coefficient
3
1.09
$\pu{cm3(g) cm-3(s) atm-1}$
1
2.805e+01
Langmuir sorption capacity parameter
4
2.805
$\pu{cm3/cm3}$
-1
2.55e-01
Affinity Coefficient
3
2.55
$\pu{atm-1}$
1
0
1.33e+00
Henry's Law Solubility Coefficient
3
1.33
$\pu{cm3(g) cm-3(s) atm-1}$
1
2.548e+01
Langmuir sorption capacity parameter
4
2.548
$\pu{cm3/cm3}$
-1
2.75e-01
Affinity Coefficient
3
2.75
$\pu{atm-1}$
2
3
Table 3. Dual mode sorption parameters for carbon dioxide in HFPC at 308 K
-1
5.9e-01
Ambient pressure
2
5.9
$\pu{MPa}$
1
3.019e+01
Solubility
4
3.019
$\pu{V_{1}/V_{2}}$
1
-1
8.8e-01
Ambient pressure
2
8.8
$\pu{MPa}$
1
3.646e+01
Solubility
4
3.646
$\pu{V_{1}/V_{2}}$
2
0
1.20e+00
Ambient pressure
3
1.20
$\pu{MPa}$
1
4.207e+01
Solubility
4
4.207
$\pu{V_{1}/V_{2}}$
3
0
1.54e+00
Ambient pressure
3
1.54
$\pu{MPa}$
1
4.617e+01
Solubility
4
4.617
$\pu{V_{1}/V_{2}}$
4
0
1.83e+00
Ambient pressure
3
1.83
$\pu{MPa}$
1
4.961e+01
Solubility
4
4.961
$\pu{V_{1}/V_{2}}$
5
0
2.08e+00
Ambient pressure
3
2.08
$\pu{MPa}$
1
5.241e+01
Solubility
4
5.241
$\pu{V_{1}/V_{2}}$
6
0
2.23e+00
Ambient pressure
3
2.23
$\pu{MPa}$
1
5.370e+01
Solubility
4
5.370
$\pu{V_{1}/V_{2}}$
7
0
2.39e+00
Ambient pressure
3
2.39
$\pu{MPa}$
1
5.499e+01
Solubility
4
5.499
$\pu{V_{1}/V_{2}}$
8
0
2.63e+00
Ambient pressure
3
2.63
$\pu{MPa}$
1
5.714e+01
Solubility
4
5.714
$\pu{V_{1}/V_{2}}$
9
0
2.89e+00
Ambient pressure
3
2.89
$\pu{MPa}$
1
5.907e+01
Solubility
4
5.907
$\pu{V_{1}/V_{2}}$
10
0
3.12e+00
Ambient pressure
3
3.12
$\pu{MPa}$
1
6.057e+01
Solubility
4
6.057
$\pu{V_{1}/V_{2}}$
11
0
3.29e+00
Ambient pressure
3
3.29
$\pu{MPa}$
1
6.142e+01
Solubility
4
6.142
$\pu{V_{1}/V_{2}}$
12
-1
3.2e-01
Ambient pressure
2
3.2
$\pu{MPa}$
1
1.348e+01
Solubility
4
1.348
$\pu{V_{1}/V_{2}}$
13
-1
6.9e-01
Ambient pressure
2
6.9
$\pu{MPa}$
1
2.083e+01
Solubility
4
2.083
$\pu{V_{1}/V_{2}}$
14
0
1.03e+00
Ambient pressure
3
1.03
$\pu{MPa}$
1
2.623e+01
Solubility
4
2.623
$\pu{V_{1}/V_{2}}$
15
0
1.37e+00
Ambient pressure
3
1.37
$\pu{MPa}$
1
3.076e+01
Solubility
4
3.076
$\pu{V_{1}/V_{2}}$
16
0
1.63e+00
Ambient pressure
3
1.63
$\pu{MPa}$
1
3.660e+01
Solubility
4
3.660
$\pu{V_{1}/V_{2}}$
17
0
1.91e+00
Ambient pressure
3
1.91
$\pu{MPa}$
1
4.070e+01
Solubility
4
4.070
$\pu{V_{1}/V_{2}}$
18
0
2.11e+00
Ambient pressure
3
2.11
$\pu{MPa}$
1
4.372e+01
Solubility
4
4.372
$\pu{V_{1}/V_{2}}$
19
0
2.37e+00
Ambient pressure
3
2.37
$\pu{MPa}$
1
4.782e+01
Solubility
4
4.782
$\pu{V_{1}/V_{2}}$
20
0
2.60e+00
Ambient pressure
3
2.60
$\pu{MPa}$
1
5.128e+01
Solubility
4
5.128
$\pu{V_{1}/V_{2}}$
21
0
2.77e+00
Ambient pressure
3
2.77
$\pu{MPa}$
1
5.343e+01
Solubility
4
5.343
$\pu{V_{1}/V_{2}}$
22
0
2.94e+00
Ambient pressure
3
2.94
$\pu{MPa}$
1
5.624e+01
Solubility
4
5.624
$\pu{V_{1}/V_{2}}$
23
0
3.09e+00
Ambient pressure
3
3.09
$\pu{MPa}$
1
5.840e+01
Solubility
4
5.840
$\pu{V_{1}/V_{2}}$
24
0
3.29e+00
Ambient pressure
3
3.29
$\pu{MPa}$
1
6.142e+01
Solubility
4
6.142
$\pu{V_{1}/V_{2}}$
25
1
Table 1. Sorption and desorption isotherms of carbon dioxide in HFPC at 308 K (The original data were represented graphically)
1
1.640e+01
Sorption
4
1.640
$\pu{V_{1}/V_{2}}$
-1
3.6e-01
Pressure
2
3.6
$\pu{MPa}$
1
1
2.628e+01
Sorption
4
2.628
$\pu{V_{1}/V_{2}}$
-1
7.2e-01
Pressure
2
7.2
$\pu{MPa}$
2
1
3.342e+01
Sorption
4
3.342
$\pu{V_{1}/V_{2}}$
0
1.08e+00
Pressure
3
1.08
$\pu{MPa}$
3
1
3.805e+01
Sorption
4
3.805
$\pu{V_{1}/V_{2}}$
0
1.36e+00
Pressure
3
1.36
$\pu{MPa}$
4
1
4.204e+01
Sorption
4
4.204
$\pu{V_{1}/V_{2}}$
0
1.63e+00
Pressure
3
1.63
$\pu{MPa}$
5
1
4.562e+01
Sorption
4
4.562
$\pu{V_{1}/V_{2}}$
0
1.85e+00
Pressure
3
1.85
$\pu{MPa}$
6
1
4.940e+01
Sorption
4
4.940
$\pu{V_{1}/V_{2}}$
0
2.11e+00
Pressure
3
2.11
$\pu{MPa}$
7
1
5.297e+01
Sorption
4
5.297
$\pu{V_{1}/V_{2}}$
0
2.32e+00
Pressure
3
2.32
$\pu{MPa}$
8
1
5.592e+01
Sorption
4
5.592
$\pu{V_{1}/V_{2}}$
0
2.52e+00
Pressure
3
2.52
$\pu{MPa}$
9
1
5.865e+01
Sorption
4
5.865
$\pu{V_{1}/V_{2}}$
0
2.68e+00
Pressure
3
2.68
$\pu{MPa}$
10
1
6.138e+01
Sorption
4
6.138
$\pu{V_{1}/V_{2}}$
0
2.82e+00
Pressure
3
2.82
$\pu{MPa}$
11
2
Table 2. Sorption isotherms of carbon dioxide in HFPC at 308 K in fugacity basis (The original data were represented graphically)
Solubility, Solubility data series
Pressure decay sorption cell and procedure were described in [1].
The International Union of Pure and Applied Chemistry
Fleming, G. K.; Koros, W. J.; Macromolecules 19, 2285 (1986).
paper
https://doi.org/10.1021/ma00162a030
Fleming, G. K.; Koros, W. J.; J. Polym. Sci. B: Polym. Phys. 28, 1137 (1990).
paper
https://doi.org/10.1002/polb.1990.090280711
124-38-9
1
CO2
InChI=1S/CO2/c2-1-3
CURLTUGMZLYLDI-UHFFFAOYSA-N
44.0095
Carbon dioxide
HFPC: Dow Chemical Co., $\rho = \pu{1.478 g mL-1}$, $T_{\rm{g}}$ = 445 K, $d$ spacing 5.8 Å (WAXD method). The polymer was conditioned before measurement of sorption isotherms by exposing to $\ce{CO2}$ at 33 atm.
32291-26-2
2
None
0.0
Hexafluorpolycarbonate (HFPC)
Carbon dioxide with Hexafluorpolycarbonate (HFPC)
Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Hexafluorpolycarbonate (HFPC)