{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Hexafluorpolycarbonate (HFPC)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Valerii I. Bondar", "sources": [{"citation": "Fleming, G. K.; Koros, W. J.; J. Polym. Sci. B: Polym. Phys. 28, 1137 (1990).", "pubtype": "paper", "url": "https://doi.org/10.1002/polb.1990.090280711"}], "system": "Carbon dioxide with Hexafluorpolycarbonate (HFPC)", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "HFPC: Dow Chemical Co., $\\rho = \\pu{1.478 g mL-1}$, $T_{\\rm{g}}$ = 445 K, $d$ spacing 5.8 \u212b (WAXD method). The polymer was conditioned before measurement of sorption isotherms by exposing to $\\ce{CO2}$ at 33 atm."}, {"constituent": 2, "name": "Hexafluorpolycarbonate (HFPC)", "formula": null, "molweight": 0.0, "casrn": "32291-26-2"}], "method": "Pressure decay sorption cell and procedure were described in [1].", "reference": {"citation": "Fleming, G. K.; Koros, W. J.; Macromolecules 19, 2285 (1986).", "pubtype": "paper", "url": "https://doi.org/10.1021/ma00162a030"}, "dataset": [{"series": 3, "title": "Table 3. Dual mode sorption parameters for carbon dioxide in HFPC at 308 K", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.09e+00", "significand": "1.09", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "2.805e+01", "significand": "2.805", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.55e-01", "significand": "2.55", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "1.33e+00", "significand": "1.33", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "2.548e+01", "significand": "2.548", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.75e-01", "significand": "2.75", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}, {"series": 1, "title": "Table 1. Sorption and desorption isotherms of carbon dioxide in HFPC at 308 K (The original data were represented graphically)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.9e-01", "significand": "5.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "3.019e+01", "significand": "3.019", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Ambient pressure", "number": "8.8e-01", "significand": "8.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "3.646e+01", "significand": "3.646", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.20e+00", "significand": "1.20", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.207e+01", "significand": "4.207", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.54e+00", "significand": "1.54", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.617e+01", "significand": "4.617", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.83e+00", "significand": "1.83", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.961e+01", "significand": "4.961", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.08e+00", "significand": "2.08", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.241e+01", "significand": "5.241", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.23e+00", "significand": "2.23", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.370e+01", "significand": "5.370", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.39e+00", "significand": "2.39", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.499e+01", "significand": "5.499", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.63e+00", "significand": "2.63", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.714e+01", "significand": "5.714", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.89e+00", "significand": "2.89", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.907e+01", "significand": "5.907", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.12e+00", "significand": "3.12", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "6.057e+01", "significand": "6.057", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 12, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.29e+00", "significand": "3.29", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "6.142e+01", "significand": "6.142", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 13, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.2e-01", "significand": "3.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "1.348e+01", "significand": "1.348", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 14, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.9e-01", "significand": "6.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "2.083e+01", "significand": "2.083", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 15, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.03e+00", "significand": "1.03", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "2.623e+01", "significand": "2.623", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 16, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.37e+00", "significand": "1.37", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "3.076e+01", "significand": "3.076", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 17, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.63e+00", "significand": "1.63", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "3.660e+01", "significand": "3.660", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 18, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.91e+00", "significand": "1.91", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.070e+01", "significand": "4.070", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 19, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.11e+00", "significand": "2.11", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.372e+01", "significand": "4.372", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 20, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.37e+00", "significand": "2.37", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "4.782e+01", "significand": "4.782", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 21, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.60e+00", "significand": "2.60", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.128e+01", "significand": "5.128", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 22, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.77e+00", "significand": "2.77", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.343e+01", "significand": "5.343", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 23, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.94e+00", "significand": "2.94", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.624e+01", "significand": "5.624", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 24, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.09e+00", "significand": "3.09", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "5.840e+01", "significand": "5.840", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}, {"pntnum": 25, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.29e+00", "significand": "3.29", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Solubility", "number": "6.142e+01", "significand": "6.142", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}], "supplemental": []}]}, {"series": 2, "title": "Table 2. Sorption isotherms of carbon dioxide in HFPC at 308 K in fugacity basis (The original data were represented graphically)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Sorption", "number": "1.640e+01", "significand": "1.640", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "3.6e-01", "significand": "3.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Sorption", "number": "2.628e+01", "significand": "2.628", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "7.2e-01", "significand": "7.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Sorption", "number": "3.342e+01", "significand": "3.342", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.08e+00", "significand": "1.08", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Sorption", "number": "3.805e+01", "significand": "3.805", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.36e+00", "significand": "1.36", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Sorption", "number": "4.204e+01", "significand": "4.204", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.63e+00", "significand": "1.63", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Sorption", "number": "4.562e+01", "significand": "4.562", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "1.85e+00", "significand": "1.85", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Sorption", "number": "4.940e+01", "significand": "4.940", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.11e+00", "significand": "2.11", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Sorption", "number": "5.297e+01", "significand": "5.297", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.32e+00", "significand": "2.32", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Sorption", "number": "5.592e+01", "significand": "5.592", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.52e+00", "significand": "2.52", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Sorption", "number": "5.865e+01", "significand": "5.865", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.68e+00", "significand": "2.68", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Sorption", "number": "6.138e+01", "significand": "6.138", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{2}}$"}, {"property": "Pressure", "number": "2.82e+00", "significand": "2.82", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}], "supplemental": []}]}]}}