Alexandre K. Bokarev
-2
8e-02
Ambient pressure
1
8
$\pu{MPa}$
-1
1.8e-01
Sorption
2
1.8
$\pu{V_{1}/V_{2}}$
1
-1
1.1e-01
Ambient pressure
2
1.1
$\pu{MPa}$
-1
2.1e-01
Sorption
2
2.1
$\pu{V_{1}/V_{2}}$
2
-1
1.4e-01
Ambient pressure
2
1.4
$\pu{MPa}$
-1
2.7e-01
Sorption
2
2.7
$\pu{V_{1}/V_{2}}$
3
-1
1.9e-01
Ambient pressure
2
1.9
$\pu{MPa}$
-1
4.2e-01
Sorption
2
4.2
$\pu{V_{1}/V_{2}}$
4
-1
3.0e-01
Ambient pressure
2
3.0
$\pu{MPa}$
-1
5.8e-01
Sorption
2
5.8
$\pu{V_{1}/V_{2}}$
5
-1
4.0e-01
Ambient pressure
2
4.0
$\pu{MPa}$
-1
6.9e-01
Sorption
2
6.9
$\pu{V_{1}/V_{2}}$
6
-1
6.0e-01
Ambient pressure
2
6.0
$\pu{MPa}$
0
1.03e+00
Sorption
3
1.03
$\pu{V_{1}/V_{2}}$
7
-1
7.5e-01
Ambient pressure
2
7.5
$\pu{MPa}$
0
1.34e+00
Sorption
3
1.34
$\pu{V_{1}/V_{2}}$
8
-1
9.0e-01
Ambient pressure
2
9.0
$\pu{MPa}$
0
1.58e+00
Sorption
3
1.58
$\pu{V_{1}/V_{2}}$
9
0
1.14e+00
Ambient pressure
3
1.14
$\pu{MPa}$
0
1.85e+00
Sorption
3
1.85
$\pu{V_{1}/V_{2}}$
10
0
1.29e+00
Ambient pressure
3
1.29
$\pu{MPa}$
0
2.01e+00
Sorption
3
2.01
$\pu{V_{1}/V_{2}}$
11
0
1.37e+00
Ambient pressure
3
1.37
$\pu{MPa}$
0
2.14e+00
Sorption
3
2.14
$\pu{V_{1}/V_{2}}$
12
0
1.44e+00
Ambient pressure
3
1.44
$\pu{MPa}$
0
2.21e+00
Sorption
3
2.21
$\pu{V_{1}/V_{2}}$
13
0
1.63e+00
Ambient pressure
3
1.63
$\pu{MPa}$
0
2.47e+00
Sorption
3
2.47
$\pu{V_{1}/V_{2}}$
14
0
1.82e+00
Ambient pressure
3
1.82
$\pu{MPa}$
0
2.72e+00
Sorption
3
2.72
$\pu{V_{1}/V_{2}}$
15
0
2.03e+00
Ambient pressure
3
2.03
$\pu{MPa}$
0
2.96e+00
Sorption
3
2.96
$\pu{V_{1}/V_{2}}$
16
0
2.25e+00
Ambient pressure
3
2.25
$\pu{MPa}$
0
3.18e+00
Sorption
3
3.18
$\pu{V_{1}/V_{2}}$
17
0
2.29e+00
Ambient pressure
3
2.29
$\pu{MPa}$
0
3.24e+00
Sorption
3
3.24
$\pu{V_{1}/V_{2}}$
18
0
2.49e+00
Ambient pressure
3
2.49
$\pu{MPa}$
0
3.50e+00
Sorption
3
3.50
$\pu{V_{1}/V_{2}}$
19
0
2.60e+00
Ambient pressure
3
2.60
$\pu{MPa}$
0
3.57e+00
Sorption
3
3.57
$\pu{V_{1}/V_{2}}$
20
0
2.59e+00
Ambient pressure
3
2.59
$\pu{MPa}$
0
3.63e+00
Sorption
3
3.63
$\pu{V_{1}/V_{2}}$
21
1
Sorption parameters of nitrogen in polycarbonate at 308 K (The original data were represented graphically)
Solubility, Solubility data series
Measurement of gas solubility was performed using a pressure decay method with a dual-volume dual transducers system (see also [1]). In order to achieve superior precision the ratio of the two working volumes should be close to 1. It was shown that the reduction of the ratio from 9.7 to 1.45 resulted in much less scatter.
The International Union of Pure and Applied Chemistry
Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.
paper
https://doi.org/10.1002/pol.1976.180140410
Koros, W. J.; Paul, D. R.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 1903.
paper
https://doi.org/10.1002/pol.1976.180141014
7727-37-9
1
N2
InChI=1S/N2/c1-2
IJGRMHOSHXDMSA-UHFFFAOYSA-N
28.0134
Nitrogen (Molecule)
$\ce{N2}$: purity >99%. PC (Bisphenol A polycarbonate): Lexan, General Electric Co., $M_{\rm{w}}$ = 35800.
25037-45-0
2
(C16H18O5)n
InChI=1S/C15H16O2.CH2O3/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;2-1(3)4/h3-10,16-17H,1-2H3;(H2,2,3,4)
XSXWYGABGYBZRM-UHFFFAOYSA-N
290.31
Polycarbonate (PC)
Nitrogen with Polycarbonate (PC)
Solubility data from IUPAC SDS Volume 70 (page ?) - Nitrogen with Polycarbonate (PC)