{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide with Polycarbonate (PC) and Copolyester (Kodar A-150)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Alexandre K. Bokarev", "sources": [{"citation": "Masi, P.; Paul, D. R.; Barlow, J. W.; J. Polym. Sci. B: Polym. Phys. 20, 15 (1982).", "pubtype": "paper", "url": "https://doi.org/10.1002/pol.1982.180200102"}], "system": "Carbon dioxide with Polycarbonate (PC) and Copolyester (Kodar A-150)", "substances": [{"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N", "sample": "Copolyester (Kodar A-150): Products, Inc. contained the units of isophthalic and terephthalic acid in a ratio 20/80; $M_{\\rm{n}}$ = 22 000, $T_{\\rm{g}}$ = 360 K.<br/>PC (Bisphenol A Polycarbonate): Lexan 131-111 General Electric Co., $M_{\\rm{n}}$ = 13 300, $M_{\\rm{w}}$ = 34 200, $T_{\\rm{g}}$ = 421 K. The blends were produced by extrusion at 293 K (above $T_{\\rm{m}}$ of the copolyester)."}, {"constituent": 2, "name": "Polycarbonate (PC)", "formula": "(C16H18O5)n", "molweight": 290.31, "casrn": "25037-45-0", "inchi": "InChI=1S/C15H16O2.CH2O3/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;2-1(3)4/h3-10,16-17H,1-2H3;(H2,2,3,4)", "inchikey": "XSXWYGABGYBZRM-UHFFFAOYSA-N"}, {"constituent": 3, "name": "Poly(1,4-cyclohexylene-dimethylene terephthalate/isophthalate)", "formula": null, "molweight": 0.0, "casrn": "poly-008"}], "method": "Sorption was measured using a pressure decay method described in [1]. The specimens were exposed to $\\ce{CO2}$ at 20 atm for one day.", "reference": {"citation": "Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.", "pubtype": "paper", "url": "https://doi.org/10.1002/pol.1976.180140410"}, "dataset": [{"series": 1, "title": "Table 1. Dual mode sorption parameters for CO<sub>2</sub> in polycarbonate-copolyester blends at 308 K (taken from the plot by the compiler)", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.44e-01", "significand": "6.44", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "9.4e+00", "significand": "9.4", "exponent": "0", "sigfigs": "2", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.9e-01", "significand": "2.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.13e-01", "significand": "6.13", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.31e+01", "significand": "1.31", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.3e-01", "significand": "2.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.13e-01", "significand": "6.13", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.38e+01", "significand": "1.38", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.8e-01", "significand": "2.8", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.55e-01", "significand": "6.55", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.80e+01", "significand": "1.80", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.3e-01", "significand": "2.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "6.86e-01", "significand": "6.86", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.92e+01", "significand": "1.92", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.6e-01", "significand": "2.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}, {"series": 2, "title": "Table 2. Sorption isotherms of carbon dioxide in polycarbonate-copolyester blends at 308 K", "points": [{"pntnum": 1, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9e-02", "significand": "9", "exponent": "-2", "sigfigs": "1", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.57e+00", "significand": "2.57", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.3e-01", "significand": "1.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "3.34e+00", "significand": "3.34", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.7e-01", "significand": "1.7", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "4.05e+00", "significand": "4.05", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.1e-01", "significand": "2.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "4.88e+00", "significand": "4.88", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.1e-01", "significand": "3.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "6.18e+00", "significand": "6.18", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [], "data": [{"property": "Ambient pressure", "number": "4.3e-01", "significand": "4.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "8.01e+00", "significand": "8.01", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 7, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.9e-01", "significand": "5.9", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "9.71e+00", "significand": "9.71", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 8, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.1e-01", "significand": "7.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.075e+01", "significand": "1.075", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 9, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9.2e-01", "significand": "9.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.286e+01", "significand": "1.286", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 10, "conditions": [], "data": [{"property": "Ambient pressure", "number": "9.4e-01", "significand": "9.4", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.249e+01", "significand": "1.249", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 11, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.05e+00", "significand": "1.05", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.378e+01", "significand": "1.378", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 12, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.25e+00", "significand": "1.25", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.528e+01", "significand": "1.528", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 13, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.28e+00", "significand": "1.28", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.576e+01", "significand": "1.576", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 14, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.35e+00", "significand": "1.35", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.616e+01", "significand": "1.616", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 15, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.47e+00", "significand": "1.47", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.739e+01", "significand": "1.739", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 16, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.67e+00", "significand": "1.67", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.847e+01", "significand": "1.847", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 17, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.74e+00", "significand": "1.74", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.929e+01", "significand": "1.929", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 18, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.75e+00", "significand": "1.75", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.868e+01", "significand": "1.868", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 19, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.86e+00", "significand": "1.86", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.967e+01", "significand": "1.967", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 20, "conditions": [], "data": [{"property": "Ambient pressure", "number": "2.08e+00", "significand": "2.08", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.111e+01", "significand": "2.111", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 21, "conditions": [], "data": [{"property": "Ambient pressure", "number": "4.2e-01", "significand": "4.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "8.50e+00", "significand": "8.50", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 22, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.1e-01", "significand": "5.1", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "9.73e+00", "significand": "9.73", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 23, "conditions": [], "data": [{"property": "Ambient pressure", "number": "5.6e-01", "significand": "5.6", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.099e+01", "significand": "1.099", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 24, "conditions": [], "data": [{"property": "Ambient pressure", "number": "6.0e-01", "significand": "6.0", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.103e+01", "significand": "1.103", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 25, "conditions": [], "data": [{"property": "Ambient pressure", "number": "7.3e-01", "significand": "7.3", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.268e+01", "significand": "1.268", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 26, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.01e+00", "significand": "1.01", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.561e+01", "significand": "1.561", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 27, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.11e+00", "significand": "1.11", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.642e+01", "significand": "1.642", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 28, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.21e+00", "significand": "1.21", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.729e+01", "significand": "1.729", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 29, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.36e+00", "significand": "1.36", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.766e+01", "significand": "1.766", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 30, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.34e+00", "significand": "1.34", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.809e+01", "significand": "1.809", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 31, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.48e+00", "significand": "1.48", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.901e+01", "significand": "1.901", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 32, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.51e+00", "significand": "1.51", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.973e+01", "significand": "1.973", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 33, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.58e+00", "significand": "1.58", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "1.946e+01", "significand": "1.946", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 34, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.66e+00", "significand": "1.66", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.040e+01", "significand": "2.040", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 35, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.96e+00", "significand": "1.96", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.235e+01", "significand": "2.235", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 36, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.79e+00", "significand": "1.79", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.175e+01", "significand": "2.175", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 37, "conditions": [], "data": [{"property": "Ambient pressure", "number": "1.90e+00", "significand": "1.90", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "2.213e+01", "significand": "2.213", "exponent": "1", "sigfigs": "4", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 38, "conditions": [], "data": [{"property": "Ambient pressure", "number": "3.2e-01", "significand": "3.2", "exponent": "-1", "sigfigs": "2", "unit": "$\\pu{MPa}$"}, {"property": "Sorption", "number": "8.53e+00", "significand": "8.53", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{V_{1}/V_{3}}$"}], "supplemental": []}, {"pntnum": 39, "conditions": [], "data": [{"property": "Ambient pressure", "number": "4.2e-01", "significand": "4.2", "exponent": "-1", "sigfigs": 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