{"compilation": {"title": "Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide, Methane and Polycarbonate (PC)", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Yuri P. Yampol'skii", "sources": [{"citation": "Sada, E.; Kumazawa, H.; Yakushiji, H.; Bamba, Y.; Sakata, K.; Wang, S. -T.; Ind. Eng. Chem. Res. 26, 433-438 (1987).", "pubtype": "paper", "url": "https://doi.org/10.1021/ie00063a006"}], "system": "Carbon dioxide, Methane and Polycarbonate (PC)", "substances": [{"constituent": 2, "name": "Polycarbonate (PC)", "formula": "(C16H18O5)n", "molweight": 290.31, "casrn": "25037-45-0", "inchi": "InChI=1S/C15H16O2.CH2O3/c1-15(2,11-3-7-13(16)8-4-11)12-5-9-14(17)10-6-12;2-1(3)4/h3-10,16-17H,1-2H3;(H2,2,3,4)", "inchikey": "XSXWYGABGYBZRM-UHFFFAOYSA-N", "sample": "PC films were provided by Teijin Co."}, {"constituent": 1, "name": "Carbon dioxide", "formula": "CO2", "molweight": 44.0095, "casrn": "124-38-9", "inchi": "InChI=1S/CO2/c2-1-3", "inchikey": "CURLTUGMZLYLDI-UHFFFAOYSA-N"}, {"constituent": 1, "name": "Methane", "formula": "CH4", "molweight": 16.0425, "casrn": "74-82-8", "inchi": "InChI=1S/CH4/h1H4", "inchikey": "VNWKTOKETHGBQD-UHFFFAOYSA-N"}], "method": "Equilibrium sorption was measured by the pressure decay method in the cell similar to one described in [1]. The pressure changes in the cell were continuously measured by a pressure transducer.", "reference": {"citation": "Koros, W. J.; Paul, D. R.; Rocha, A. A.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 687.", "pubtype": "paper", "url": "https://doi.org/10.1002/pol.1976.180140410"}, "dataset": [{"series": 1, "title": "Dual-mode sorption parameters", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.93e+02", "significand": "2.93", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "9.11e-01", "significand": "9.11", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "2.31e+01", "significand": "2.31", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "2.64e-01", "significand": "2.64", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "3.03e+02", "significand": "3.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "8.04e-01", "significand": "8.04", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.99e+01", "significand": "1.99", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.97e-01", "significand": "1.97", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "3.13e+02", "significand": "3.13", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "7.02e-01", "significand": "7.02", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "1.60e+01", "significand": "1.60", "exponent": "1", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.24e-01", "significand": "1.24", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.93e+02", "significand": "2.93", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "3.35e-01", "significand": "3.35", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "6.40e+00", "significand": "6.40", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.57e-01", "significand": "1.57", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.03e+02", "significand": "3.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "3.08e-01", "significand": "3.08", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "5.62e+00", "significand": "5.62", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "1.20e-01", "significand": "1.20", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.13e+02", "significand": "3.13", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Henry's Law Solubility Coefficient", "number": "2.80e-01", "significand": "2.80", "exponent": "-1", "sigfigs": "3", "unit": "$\\pu{cm3(g) cm-3(s) atm-1}$"}, {"property": "Langmuir sorption capacity parameter", "number": "4.72e+00", "significand": "4.72", "exponent": "0", "sigfigs": "3", "unit": "$\\pu{cm3/cm3}$"}, {"property": "Affinity Coefficient", "number": "8.72e-02", "significand": "8.72", "exponent": "-2", "sigfigs": "3", "unit": "$\\pu{atm-1}$"}], "supplemental": []}]}]}}