Yuri P. Yampol'skii
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
1.05e-01
Henry's Law Solubility Coefficient
3
1.05
$\pu{cm3(STP) cm-3 cmHg-1}$
0
2.17e+00
Amount concentration (1)
3
2.17
$\pu{cm3/cm3}$
-2
4.91e-02
Affinity Coefficient
3
4.91
$\pu{atm-1}$
1
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
1.84e-01
Henry's Law Solubility Coefficient
3
1.84
$\pu{cm3(g) cm-3(s) atm-1}$
1
4.03e+01
Amount concentration (1)
3
4.03
$\pu{cm3/cm3}$
-2
4.96e-02
Affinity Coefficient
3
4.96
$\pu{atm-1}$
2
1
Table 1. Dual mode sorption parameters for methane and carbon dioxide in PVC at 298 K
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
1.7e-01
Ambient pressure
2
1.7
$\pu{MPa}$
-1
3.8e-01
Sorption
2
3.8
$\pu{V_{1}/V_{2}}$
1
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
3.4e-01
Ambient pressure
2
3.4
$\pu{MPa}$
-1
5.3e-01
Sorption
2
5.3
$\pu{V_{1}/V_{2}}$
2
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
4.7e-01
Ambient pressure
2
4.7
$\pu{MPa}$
-1
8.5e-01
Sorption
2
8.5
$\pu{V_{1}/V_{2}}$
3
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
5.5e-01
Ambient pressure
2
5.5
$\pu{MPa}$
0
1.11e+00
Sorption
3
1.11
$\pu{V_{1}/V_{2}}$
4
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
6.7e-01
Ambient pressure
2
6.7
$\pu{MPa}$
0
1.13e+00
Sorption
3
1.13
$\pu{V_{1}/V_{2}}$
5
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
7.8e-01
Ambient pressure
2
7.8
$\pu{MPa}$
0
1.42e+00
Sorption
3
1.42
$\pu{V_{1}/V_{2}}$
6
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
8.8e-01
Ambient pressure
2
8.8
$\pu{MPa}$
0
1.61e+00
Sorption
3
1.61
$\pu{V_{1}/V_{2}}$
7
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
9.8e-01
Ambient pressure
2
9.8
$\pu{MPa}$
0
1.67e+00
Sorption
3
1.67
$\pu{V_{1}/V_{2}}$
8
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
0
1.06e+00
Ambient pressure
3
1.06
$\pu{MPa}$
0
1.83e+00
Sorption
3
1.83
$\pu{V_{1}/V_{2}}$
9
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
0
1.16e+00
Ambient pressure
3
1.16
$\pu{MPa}$
0
1.95e+00
Sorption
3
1.95
$\pu{V_{1}/V_{2}}$
10
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
1.6e-01
Ambient pressure
2
1.6
$\pu{MPa}$
0
3.48e+00
Sorption
3
3.48
$\pu{V_{1}/V_{2}}$
11
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
2.7e-01
Ambient pressure
2
2.7
$\pu{MPa}$
0
5.28e+00
Sorption
3
5.28
$\pu{V_{1}/V_{2}}$
12
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
4.1e-01
Ambient pressure
2
4.1
$\pu{MPa}$
0
7.74e+00
Sorption
3
7.74
$\pu{V_{1}/V_{2}}$
13
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
5.4e-01
Ambient pressure
2
5.4
$\pu{MPa}$
0
9.71e+00
Sorption
3
9.71
$\pu{V_{1}/V_{2}}$
14
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
6.4e-01
Ambient pressure
2
6.4
$\pu{MPa}$
1
1.098e+01
Sorption
4
1.098
$\pu{V_{1}/V_{2}}$
15
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
7.7e-01
Ambient pressure
2
7.7
$\pu{MPa}$
1
1.272e+01
Sorption
4
1.272
$\pu{V_{1}/V_{2}}$
16
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
-1
8.8e-01
Ambient pressure
2
8.8
$\pu{MPa}$
1
1.399e+01
Sorption
4
1.399
$\pu{V_{1}/V_{2}}$
17
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
0
1.00e+00
Ambient pressure
3
1.00
$\pu{MPa}$
1
1.527e+01
Sorption
4
1.527
$\pu{V_{1}/V_{2}}$
18
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
0
1.14e+00
Ambient pressure
3
1.14
$\pu{MPa}$
1
1.694e+01
Sorption
4
1.694
$\pu{V_{1}/V_{2}}$
19
2
2.98e+02
Ambient temperature
3
2.98
$\pu{K}$
0
1.27e+00
Ambient pressure
3
1.27
$\pu{MPa}$
1
1.801e+01
Sorption
4
1.801
$\pu{V_{1}/V_{2}}$
20
2
Table 2. Sorption isotherms of methane and carbon dioxide in PVC at 298 K (The original data wre represented graphically)
Solubility, Solubility data series
Sorption isotherms were obtained by the pressure decay method. [1]. Conditioning at 23 atm for 60 h and degassing preceded the measurements.
The International Union of Pure and Applied Chemistry
Koros, W. J.; Paul, D. R.; J. Polym. Sci., Polym. Phys. Ed., 1976, 14, 1903.
paper
https://doi.org/10.1002/pol.1976.180141014
Field, J. R.; Parker, B. E; Ballard, R. L.; Japan-US Polymer Symposium, pp. 247-248 (1985).
symposium
9002-86-2
2
(C2H3Cl)n
InChI=1S/C2H3Cl/c1-2-3/h2H,1H2
BZHJMEDXRYGGRV-UHFFFAOYSA-N
62.5
Poly(vinyl chloride) (PVC)
PVC: Samples were compression modeled at 450 K from a mixture of low molecular mass PVC resin and 3% of a stabilizer (Cincinnati Milacorn (TM-692)).
124-38-9
1
CO2
InChI=1S/CO2/c2-1-3
CURLTUGMZLYLDI-UHFFFAOYSA-N
44.0095
Carbon dioxide
74-82-8
1
CH4
InChI=1S/CH4/h1H4
VNWKTOKETHGBQD-UHFFFAOYSA-N
16.0425
Methane
Carbon dioxide, Methane and Poly(vinyl chloride) (PVC)
Solubility data from IUPAC SDS Volume 70 (page ?) - Carbon dioxide, Methane and Poly(vinyl chloride) (PVC)