{"compilation": {"title": "Solubility data from IUPAC SDS Volume 37 (page 271) - Cyclohexane with Deuterium oxide", "publisher": "The International Union of Pure and Applied Chemistry", "keywords": "Solubility, Solubility data series", "compilers": "Andrzej Maczynski", "sources": [{"citation": "Backx, P.; Goldman, S.; J. Phys. Chem. 1981, 85, 2975-9.", "pubtype": "paper", "url": "https://doi.org/10.1021/j150620a026"}], "system": "Cyclohexane with Deuterium oxide", "substances": [{"constituent": 1, "name": "Cyclohexane", "formula": "C6H12", "molweight": 84.1595, "casrn": "110-82-7", "inchi": "InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2", "inchikey": "XDTMQSROBMDMFD-UHFFFAOYSA-N", "sample": "Certified grade; washed with water, dried with silica gel, and distilled; $d^{25}$ = 0.77390."}, {"constituent": 2, "name": "Water-d2", "formula": "D2O", "molweight": 20.0276, "casrn": "7789-20-0", "inchi": "InChI=1S/H2O/h1H2/i/hD2", "inchikey": "XLYOFNOQVPJJNP-ZSJDYOACSA-N", "sample": "obtained from the manufacturer; minimum isotopic purity of 99.7 atom% D."}], "method": "In a 175-mL milk-dilution bottle fitted with a Bakelite screw cap and a Teflon insert and rotated end-over-end, (1) was equilibrated with an excess of (2), sampled with Hamilton syringes and titrated in an Aquatest II automatic Karl Fischer Titrator.", "dataset": [{"series": 1, "title": "Solubility of deuterium oxide in cyclohexane", "points": [{"pntnum": 1, "conditions": [{"property": "Ambient temperature", "number": "2.83e+02", "significand": "2.83", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "1.57e-04", "significand": "1.57", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "3.74e-05", "significand": "3.74", "exponent": "-5", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 2, "conditions": [{"property": "Ambient temperature", "number": "2.88e+02", "significand": "2.88", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "1.81e-04", "significand": "1.81", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "4.31e-05", "significand": "4.31", "exponent": "-5", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 3, "conditions": [{"property": "Ambient temperature", "number": "2.93e+02", "significand": "2.93", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "2.42e-04", "significand": "2.42", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "5.76e-05", "significand": "5.76", "exponent": "-5", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 4, "conditions": [{"property": "Ambient temperature", "number": "2.98e+02", "significand": "2.98", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "2.80e-04", "significand": "2.80", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "6.66e-05", "significand": "6.66", "exponent": "-5", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 5, "conditions": [{"property": "Ambient temperature", "number": "3.03e+02", "significand": "3.03", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "3.61e-04", "significand": "3.61", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "8.59e-05", "significand": "8.59", "exponent": "-5", "sigfigs": "3", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 6, "conditions": [{"property": "Ambient temperature", "number": "3.08e+02", "significand": "3.08", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "4.64e-04", "significand": "4.64", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "1.104e-04", "significand": "1.104", "exponent": "-4", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}, {"pntnum": 7, "conditions": [{"property": "Ambient temperature", "number": "3.13e+02", "significand": "3.13", "exponent": "2", "sigfigs": "3", "unit": "$\\pu{K}$"}], "data": [{"property": "Mole fraction - Liquid (2)", "number": "5.35e-04", "significand": "5.35", "exponent": "-4", "sigfigs": "3", "unit": "1"}], "supplemental": [{"property": "Relative mass - solution (2)", "number": "1.274e-04", "significand": "1.274", "exponent": "-4", "sigfigs": "4", "unit": "g<sub>2</sub>/100 g sln"}]}]}]}}