Colin L. Young 2 3.391e+02 Ambient temperature 4 3.391 $\pu{K}$ 3 2.445e+03 Ambient pressure 4 2.445 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 1 2 3.375e+02 Ambient temperature 4 3.375 $\pu{K}$ 3 2.300e+03 Ambient pressure 4 2.300 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 2 2 3.334e+02 Ambient temperature 4 3.334 $\pu{K}$ 3 2.000e+03 Ambient pressure 4 2.000 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 3 2 3.280e+02 Ambient temperature 4 3.280 $\pu{K}$ 3 1.750e+03 Ambient pressure 4 1.750 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 4 2 3.239e+02 Ambient temperature 4 3.239 $\pu{K}$ 3 1.530e+03 Ambient pressure 4 1.530 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 5 2 3.149e+02 Ambient temperature 4 3.149 $\pu{K}$ 3 1.100e+03 Ambient pressure 4 1.100 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 6 2 3.084e+02 Ambient temperature 4 3.084 $\pu{K}$ 2 8.40e+02 Ambient pressure 3 8.40 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 7 2 3.038e+02 Ambient temperature 4 3.038 $\pu{K}$ 2 6.55e+02 Ambient pressure 3 6.55 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 8 2 3.001e+02 Ambient temperature 4 3.001 $\pu{K}$ 2 4.90e+02 Ambient pressure 3 4.90 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 9 2 2.956e+02 Ambient temperature 4 2.956 $\pu{K}$ 2 2.20e+02 Ambient pressure 3 2.20 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 10 2 3.261e+02 Ambient temperature 4 3.261 $\pu{K}$ 2 1.70e+02 Ambient pressure 3 1.70 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 11 2 3.159e+02 Ambient temperature 4 3.159 $\pu{K}$ 2 1.58e+02 Ambient pressure 3 1.58 $\pu{bar}$ -1 2.5e-01 Mole fraction - Liquid (1) 2 2.5 1 1 5.65e+01 Relative mass - solution (1) 3 5.65 g₁/100 g₂ 12 2 3.552e+02 Ambient temperature 4 3.552 $\pu{K}$ 3 2.855e+03 Ambient pressure 4 2.855 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 13 2 3.510e+02 Ambient temperature 4 3.510 $\pu{K}$ 3 2.600e+03 Ambient pressure 4 2.600 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 14 2 3.482e+02 Ambient temperature 4 3.482 $\pu{K}$ 3 2.450e+03 Ambient pressure 4 2.450 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 15 2 3.424e+02 Ambient temperature 4 3.424 $\pu{K}$ 3 2.095e+03 Ambient pressure 4 2.095 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 16 2 3.379e+02 Ambient temperature 4 3.379 $\pu{K}$ 3 1.850e+03 Ambient pressure 4 1.850 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 17 2 3.324e+02 Ambient temperature 4 3.324 $\pu{K}$ 3 1.585e+03 Ambient pressure 4 1.585 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 18 2 3.304e+02 Ambient temperature 4 3.304 $\pu{K}$ 3 1.480e+03 Ambient pressure 4 1.480 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 19 2 3.249e+02 Ambient temperature 4 3.249 $\pu{K}$ 3 1.300e+03 Ambient pressure 4 1.300 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 20 2 3.196e+02 Ambient temperature 4 3.196 $\pu{K}$ 3 1.100e+03 Ambient pressure 4 1.100 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 21 2 3.118e+02 Ambient temperature 4 3.118 $\pu{K}$ 2 7.90e+02 Ambient pressure 3 7.90 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 22 2 3.034e+02 Ambient temperature 4 3.034 $\pu{K}$ 2 5.21e+02 Ambient pressure 3 5.21 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 23 2 2.970e+02 Ambient temperature 4 2.970 $\pu{K}$ 2 3.00e+02 Ambient pressure 3 3.00 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 24 2 2.962e+02 Ambient temperature 4 2.962 $\pu{K}$ 2 2.50e+02 Ambient pressure 3 2.50 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 25 2 3.002e+02 Ambient temperature 4 3.002 $\pu{K}$ 2 1.81e+02 Ambient pressure 3 1.81 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 26 2 3.122e+02 Ambient temperature 4 3.122 $\pu{K}$ 2 1.66e+02 Ambient pressure 3 1.66 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 27 2 3.252e+02 Ambient temperature 4 3.252 $\pu{K}$ 2 1.82e+02 Ambient pressure 3 1.82 $\pu{bar}$ -1 5.46e-01 Mole fraction - Liquid (1) 3 5.46 1 1 8.24e+01 Relative mass - solution (1) 3 8.24 g₁/100 g₂ 28 2 3.303e+02 Ambient temperature 4 3.303 $\pu{K}$ 3 2.750e+03 Ambient pressure 4 2.750 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 29 2 3.274e+02 Ambient temperature 4 3.274 $\pu{K}$ 3 2.600e+03 Ambient pressure 4 2.600 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 30 2 3.229e+02 Ambient temperature 4 3.229 $\pu{K}$ 3 2.300e+03 Ambient pressure 4 2.300 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 31 2 3.189e+02 Ambient temperature 4 3.189 $\pu{K}$ 3 2.000e+03 Ambient pressure 4 2.000 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 32 2 3.100e+02 Ambient temperature 4 3.100 $\pu{K}$ 3 1.500e+03 Ambient pressure 4 1.500 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 33 2 3.131e+02 Ambient temperature 4 3.131 $\pu{K}$ 3 1.700e+03 Ambient pressure 4 1.700 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 34 2 3.044e+02 Ambient temperature 4 3.044 $\pu{K}$ 3 1.200e+03 Ambient pressure 4 1.200 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 35 2 2.989e+02 Ambient temperature 4 2.989 $\pu{K}$ 2 9.90e+02 Ambient pressure 3 9.90 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 36 2 2.964e+02 Ambient temperature 4 2.964 $\pu{K}$ 2 8.40e+02 Ambient pressure 3 8.40 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 37 2 2.881e+02 Ambient temperature 4 2.881 $\pu{K}$ 2 5.40e+02 Ambient pressure 3 5.40 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 38 2 2.810e+02 Ambient temperature 4 2.810 $\pu{K}$ 2 2.90e+02 Ambient pressure 3 2.90 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 39 2 2.754e+02 Ambient temperature 4 2.754 $\pu{K}$ 2 1.68e+02 Ambient pressure 3 1.68 $\pu{bar}$ -1 7.55e-01 Mole fraction - Liquid (1) 3 7.55 1 1 9.23e+01 Relative mass - solution (1) 3 9.23 g₁/100 g₂ 40 1 Solubility, Solubility data series Measurements were made in a steel optical cell within an aluminum block furnace. The cell contents were stirred magnetically. Pressure was measured using a movable piston and Bourdon gauge. Temperature was measured with a steel-sheathed thermocouple. Components were charged into the cell and the transition from one phase to two phases was observed visually. The International Union of Pure and Applied Chemistry Bröllos, K.; Peter, K.; Schneider, G. M.; Ber. Bunsenges. Phys. Chem. 1970, 74, 682-6. paper https://onlinelibrary.wiley.com/doi/10.1002/bbpc.19700740714 71-43-2 1 C6H6 InChI=1S/C6H6/c1-2-4-6-5-3-1/h1-6H UHOVQNZJYSORNB-UHFFFAOYSA-N 78.1118 Benzene Merck sample, purity 99.9 mole per cen. 7789-20-0 2 D2O InChI=1S/H2O/h1H2/i/hD2 XLYOFNOQVPJJNP-ZSJDYOACSA-N 20.0276 Water-d2 Isotopic purity 99.7 mole%. Benzene with Water-d2